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We present astrometric observations of the Saturnian satellites Mimas, Enceladus, Tethys, Dione and Rhea from Cassini Imaging Science Subsystem (ISS) narrow-angle camera (NAC) images. Image sequences were designed to observe mutual occultations betwe en these satellites. The positions of satellite centres were estimated by fitting ellipsoidal shape models to the measured limbs of the imaged satellites. Spacecraft pointing corrections were computed using the UCAC2 star catalogue. We provide a total of 2303 astrometric observations, resulting in 976 pairs, the remainder consisting of observations of a single satellite. Mean residuals for the individual satellite positions relative to the SAT360 ephemeris were 4.3 km in the line direction and -2.4 km in the sample direction, with standard deviations of 5.6 and 7.0 km respectively, an order of magnitude improvement in precision compared to published HST observations. By considering inter-satellite separations, uncertainties in camera pointing and spacecraft positioning along with possible biases in the individual positions of the satellites can be largely eliminated, resulting in an order-of-magnitude increase in accuracy compared to that achievable using the individual satellite positions. We show how factors relating to the viewing geometry cause small biases in the individual positions of order 0.28 pixel to become systematic across the dataset as a whole and discuss options for reducing their effects . The reduced astrometric data are provided in the form of individual positions for each satellite, together with the measured positions of reference stars, in order to allow more flexibility in the processing of the observations, taking into account possible future advances in limb-fitting techniques as well as the future availability of more accurate star catalogues, such as those from the GAIA mission.
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