We report a photoemission study at room temperature on BaFe2X3 (X = S and Se) and CsFe2Se3 in which two-leg ladders are formed by the Fe sites. The Fe 2p core-level peaks of BaFe2X3 are broad and exhibit two components, indicating that itinerant and
localized Fe 3d sites coexist similar to KxFe2-ySe2. The Fe 2p core-level peak of CsFe2Se3 is rather sharp and is accompanied by a charge-transfer satellite. The insulating ground state of CsFe2Se3 can be viewed as a Fe2+ Mott insulator in spite of the formal valence of +2.5. The itinerant versus localized behaviors can be associated with the stability of chalcogen p holes in the two-leg ladder structure.
We report experimental evidence for the phase diagram of doped cuprate superconductors as a function of the micro-strain (e) of the Cu-O bond length, measured by Cu K-edge EXAFS, and hole doping (d). This phase diagram shows a QCP at P(e*,d*) where f
or the micro-strain e larger than the critical value e* charge-orbital-spin stripes and free carriers co-exist. The superconducting phase occurs in the region of critical fluctuations around this QCP. The critical temperature is function of two variables and Tc shows its maximum at the strain driven QCP. The critical fluctuations near this strain QCP give the self-organization of a metallic superlattice of quantum wires superstripes that favors the amplification of the critical temperature.
