Frequency comparison of ${}^{171}$Yb${}^+$ ion optical clocks at PTB and NPL via GPS PPP

We used Precise Point Positioning, a well-established GPS carrier-phase frequency transfer method to perform a direct remote comparison of two optical frequency standards based on single laser-cooled $^{171}$Yb$^+$ ions operated at NPL, UK and PTB, Germany. At both institutes an active hydrogen maser serves as a flywheel oscillator; it is connected to a GPS receiver as an external frequency reference and compared simultaneously to a realization of the unperturbed frequency of the ${{}^2S_{1/2}(F=0)-{}^2D_{3/2}(F=2)}$ electric quadrupole transition in ${}^{171}$Yb${}^+$ via an optical femtosecond frequency comb. To profit from long coherent GPS link measurements we extrapolate over the various data gaps in the optical clock to maser comparisons which introduces maser noise to the frequency comparison but improves the uncertainty from the GPS link. We determined the total statistical uncertainty consisting of the GPS link uncertainty and the extrapolation uncertainties for several extrapolation schemes. Using the extrapolation scheme with the smallest combined uncertainty, we find a fractional frequency difference $y(mathrm{PTB})-y(mathrm{NPL})$ of $-1.3(1.2)times 10^{-15}$ for a total measurement time of 67 h. This result is consistent with an agreement of both optical clocks and with recent absolute frequency measurements against caesium fountain clocks.

Phase Analysis for Frequency Standards in the Microwave and Optical Domains

Coherent manipulation of atomic states is a key concept in high-precision spectroscopy and used in atomic fountain clocks and a number of optical frequency standards. Operation of these standards can involve a number of cyclic switching processes, which may induce cycle synchronous phase excursions of the interrogation signal and thus lead to shifts in the output of the frequency standard. We have built a FPGA-based phase analyzer to investigate these effects and conducted measurements on two frequency standards. For the caesium fountain PTB-CSF2 we were able to exclude phase variations of the microwave source at the level of a few $mu$rad, corresponding to relative frequency shifts of less than 10$^{-16}$. In the optical domain, we investigated phase variations in PTBs Yb$^+$ optical frequency standard and made detailed measurements of AOM chirps and their scaling with duty cycle and driving power. We ascertained that cycle-synchronous as well as long-term phase excursion do not cause frequency shifts larger than 10$^{-18}$.

Improved limit on a temporal variation of $m_p/m_e$ from comparisons of Yb$^+$ and Cs atomic clocks

Accurate measurements of different transition frequencies between atomic levels of the electronic and hyperfine structure over time are used to investigate temporal variations of the fine structure constant $alpha$ and the proton-to-electron mass ratio $mu$. We measure the frequency of the $^2S_{1/2}rightarrow {^2F_{7/2}}$ electric octupole (E3) transition in $^{171}$Yb$^+$ against two caesium fountain clocks as $f(E3) = 642,121,496,772,645.36(25)$~Hz with an improved fractional uncertainty of $3.9times 10^{-16}$. This transition frequency shows a strong sensitivity to changes of $alpha$. Together with a number of previous and recent measurements of the $^2S_{1/2}rightarrow {^2D_{3/2}}$ electric quadrupole transition in $^{171}$Yb$^+$ and with data from other elements, a least-squares analysis yields $(1/alpha)(dalpha/dt)=-0.20(20)times 10^{-16}/mathrm{yr}$ and $(1/mu)(dmu/dt)=-0.5(1.6)times 10^{-16}/mathrm{yr}$, confirming a previous limit on $dalpha/dt$ and providing the most stringent limit on $d mu/dt$ from laboratory experiments.

A Cs-Based Optical Frequency Measurement Using Cross-Linked Optical and Microwave Oscillators

We describe a measurement of the frequency of the 2S1/2(F = 0) - 2D3/2(F = 2) transition of 171Yb+ at the wavelength 436 nm (frequency 688 THz), using a single Yb+ ion confined in a Paul trap and two caesium fountains as references. In one of the fountains, the frequency of the microwave oscillator that interrogates the caesium atoms is stabilized by the laser that excites the Yb+ reference transition with a linewidth in the hertz range. The stability is transferred to the microwave oscillator with the use of a fiber laser based optical frequency comb generator that also provides the frequency conversion for the absolute frequency measurement. The frequency comb generator is configured as a transfer oscillator so that fluctuations of the pulse repetition rate and of the carrier offset frequency do not degrade the stability of the frequency conversion. The phase noise level of the generated ultrastable microwave signal is comparable to that of a cryogenic sapphire oscillator. For fountain operation with optical molasses loaded from a laser cooled atomic beam source, we obtain a stability corresponding to a fractional Allan deviation of $4.1times 10^{-14} (tau/text{s})^{-1/2}$. With the molasses loaded from thermal vapor and an averaging time of 65 h, we measure the frequency of the Yb+ transition with a relative statistical uncertainty of $2.8times10^{-16}$ and a systematic uncertainty of $5.9times10^{-16}$. The frequency was also simultaneously measured with the second fountain that uses a quartz-based interrogation oscillator. The unperturbed frequency of the Yb+ transition is realized with an uncertainty of $1.1times10^{-16}$ that mainly results from the uncertainty of the blackbody shift at the operating temperature near 300 K. The transition frequency of 688 358 979 309 307.82(36) Hz, measured with the two fountains, is in good agreement with previous results.

A generalized Ramsey excitation scheme with suppressed light shift

We experimentally investigate a recently proposed optical excitation scheme [V.I. Yudin et al., Phys. Rev. A 82, 011804(R)(2010)] that is a generalization of Ramseys method of separated oscillatory fields and consists of a sequence of three excitation pulses. The pulse sequence is tailored to produce a resonance signal which is immune to the light shift and other shifts of the transition frequency that are correlated with the interaction with the probe field. We investigate the scheme using a single trapped 171Yb+ ion and excite the highly forbidden 2S1/2-2F7/2 electric-octupole transition under conditions where the light shift is much larger than the excitation linewidth, which is in the Hertz range. The experiments demonstrate a suppression of the light shift by four orders of magnitude and an immunity against its fluctuations.

High-accuracy optical clock based on the octupole transition in 171Yb+

We experimentally investigate an optical frequency standard based on the 467 nm (642 THz) electric-octupole reference transition 2S1/2(F=0) -> F7/2(F=3) in a single trapped 171Yb+ ion. The extraordinary features of this transition result from the long natural lifetime and from the 4f136s2 configuration of the upper state. The electric quadrupole moment of the 2F7/2 state is measured as -0.041(5) e(a0)^2, where e is the elementary charge and a0 the Bohr radius. We also obtain information on the differential scalar and tensorial components of the static polarizability and of the probe light induced ac Stark shift of the octupole transition. With a real-time extrapolation scheme that eliminates this shift, the unperturbed transition frequency is realized with a fractional uncertainty of 7.1x10^(-17). The frequency is measured as 642 121 496 772 645.15(52) Hz.