A yet unknown surface reconstruction of V3Si(001), which is most likely induced by carbon, is used to investigate the quasi-particle energy gap at the atomic scale by a cryogenic scanning tunneling microscope. The width of the gap was virtually not a
ltered at and close to carbon impurities, nor did it change at different sites of the reconstructed surface lattice. A remarkable modification of the spectroscopic signature of the gap was induced, however, upon moving the tip of the microscope into controlled contact with the superconductor. Spectroscopy of the resulting normal-metal -- superconductor junction indicated the presence of Andreev reflections.
