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We consider the processes of polarization bremsstrahlung in collisions of fast ions with linear chains consisting of isolated atoms. We obtained intensities and angular distributions of radiation spectra for arbitrary number of atoms in the chain. It appeared that interference in the photon radiation amplitudes lead to prominent variation of spectral angular distributions of polarization bremsstrahlung as compared to these distribuitions in collisions with an isolated atom. The mean loss of energy due to radiation or the so-called rediative friction is estimated. The results obtained permit standard generalization to the case of polarization bremsstrahlung in fast ion chanelling above surfaces an and in solid body.
Hartree-Fock atom in a strong electric static field is considered. It is demonstrated that exchange between outer and inner electrons, taken into account by the so-called Fock term affects strongly the long-range behavior of the inner electron wave f unction. As a result, it dramatically increases its probability to be ionized. A simple model is analyzed demonstrating that the decay probability, compared to the case of a local (Hartree) atomic potential, increases by many orders of magnitude. As a result of such increase, the ratio of inner to outer electrons ionization probability became not too small. It is essential that the effect of exchange upon probability of inner electron ionization by strong electric field is proportional to the square of the number of outer electrons. It signals that in clusters the inner electron ionization by strong field, the very fact of which is manifested by e.g. high energy quanta emission, has to be essentially increased as compared to this process in gaseous atomic objects.
We discuss the complicated resonance structure of the endohedral atom photoionization cross section. Very strong enhancement and interference patterns in the photoionization cross-section of the valent and subvalent subshells of noble gas endohedral atoms A@C60 are demonstrated. It is shown also that the atomic Giant resonance can be either completely destroyed or remains almost untouched depending on the velocity of photoelectrons that are emitted in the resonances decay process. These effects are results of dynamic modification of the incoming beam of radiation due to polarization of the fullerenes electron shell and reflection of photoelectrons be the fullerenes shell static potential. We have considered the outer np- and subvalent ns-subshells for Ne, Ar, Kr and Xe noble gas atoms. The modification of the Giant resonances is considered for a whole sequence of endohedrals with atoms and ions Xe, Ba, La, Ce+, Ce+4, Eu. The polarization of the fullerene shell is expressed via the total photoabsorption cross section. The photoelectron reflection from the static potential is taken into account in the frame of the so-called bubble potential that is a spherical -type potential.
107 - M. Ya. Amusia 2007
It is demonstrated that in photoabsorption by endohedral atoms some atomic Giant resonances are almost completely destroyed while the others are totally preserved due to different action on it of the fullerenes shell. As the first example we discuss the 4d10 Giant resonance in Xe@C60 whereas as the second serves the Giant autoionization resonance in Eu@C60. The qualitative difference comes from the fact that photoelectrons from the 4d Giant resonance has small energies (tens of eV) and are strongly reflected by the C60 fullerenes shell. As to the Eu@C60, Giant autoionization leads to fast photoelectrons (about hundred eV) that go out almost untouched by the C60 shell. As a result of the outgoing electrons energy difference the atomic Giant resonances will be largely destroyed in A@C60 while the Giant autoionization resonance will be almost completely preserved. Thus, on the way from Xe@C60 Giant resonance to Eu@C60 Giant autoionization resonance the oscillation structure should disappear. Similar will be the decrease of oscillations on the way from pure Giant to pure Giant autoionization resonances for the angular anisotropy parameters. At Giant resonance frequencies the role of polarization of the fullerenes shell by the incoming photon beam is inessential. Quite different is the situation for the outer electrons in Eu@C60, the photoionization of which will be also considered.
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