We present Herschel/HIFI observations of 30 transitions of water isotopologues toward the high-mass star forming region NGC 6334 I. The line profiles of H_2^{16}O, H_2^{17}O, H_2^{18}O, and HDO show a complex pattern of emission and absorption compon
ents associated with the embedded hot cores, a lower-density envelope, two outflow components, and several foreground clouds, some associated with the NGC 6334 complex, others seen in projection against the strong continuum background of the source. Our analysis reveals an H2O ortho/para ratio of 3 +/- 0.5 in the foreground clouds, as well as the outflow. The water abundance varies from ~10^{-8} in the foreground clouds and the outer envelope to ~10^{-6} in the hot core. The hot core abundance is two orders of magnitude below the chemical model predictions for dense, warm gas, but within the range of values found in other Herschel/HIFI studies of hot cores and hot corinos. This may be related to the relatively low gas and dust temperature (~100 K), or time dependent effects, resulting in a significant fraction of water molecules still locked up in dust grain mantles. The HDO/H_2O ratio in NGC 6334 I, ~2 10^{-4}, is also relatively low, but within the range found in other high-mass star forming regions.
We present observations of twelve rotational transitions of H2O-16, H2O-18, and H2O-17 toward the massive star-forming region NGC 6334 I, carried out with Herschel/HIFI as part of the guaranteed time key program Chemical HErschel Surveys of Star form
ing regions (CHESS). We analyze these observations to obtain insights into physical processes in this region. We identify three main gas components (hot core, cold foreground, and outflow) in NGC 6334 I and derive the physical conditions in these components. The hot core, identified by the emission in highly excited lines, shows a high excitation temperature of 200 K, whereas water in the foreground component is predominantly in the ortho- and para- ground states. The abundance of water varies between 4 10^-5 (outflow) and 10^-8 (cold foreground gas). This variation is most likely due to the freeze-out of water molecules onto dust grains. The H2O-18/H2O-17 abundance ratio is 3.2, which is consistent with the O-18/O-17 ratio determined from CO isotopologues. The ortho/para ratio in water appears to be relatively low 1.6(1) in the cold, quiescent gas, but close to the equilibrium value of three in the warmer outflow material (2.5(0.8)).
NGC 2024, a sites of massive star formation, have complex internal structures caused by cal heating by young stars, outflows, and stellar winds. These complex cloud structures lead to intricate emission line shapes. The goal of this paper is to show
that the complex line shapes of 12 CO lines in NGC 2024 can be explained consistently with a model, whose temperature and velocity structure are based on the well-established scenario of a PDR and the Blister model. We present velocity-resolved spectra of seven CO lines ranging from J=3 to J=13, and we combined these data with CO high-frequency data from the ISO satellite. We find that the bulk of the molecular cloud associated with NGC 2024 consists of warm (75 K) and dense (9e5 cm-3) gas. An additional hot (~ 300 K) component, located at the interface of the HII region and the molecular cloud, is needed to explain the emission of the high-J CO lines. Deep absorption notches indicate that very cold material (20 K) exists in front of the warm material, too. A temperature and column density structure consistent with those predicted by PDR models, combined with the velocity structure of a Blister model, appropriately describes the observed emission line profiles of this massive star forming region. This case study of NGC 2024 shows that, with physical insights into these complex regions and careful modeling, multi-line observations of CO can be used to derive detailed physical conditions in massive star forming regions.
Deuterated ions are abundant in cold (T=10 K), dense (n=10^5 cm^-3) regions, in which CO is frozen out onto dust grains. In such environments, the deuterium fractionation of such ions can exceed the elemental abundance ratio of D/H by a factor of 10^
4. In this paper we use the deuterium fractionation to investigate the evolutionary state of Class 0 protostars. In a sample of 20 protostellar objects, we found a clear correlation between the N2D+/N2H+ ratio and evolutionary tracers. As expected, the coolest, i.e. the youngest, objects show the largest deuterium fractionation. Furthermore, we find that sources with a high N2D+/N2H+ ratio show clear indication for infall.
