The seasonal evolution of Saturns polar atmospheric temperatures and hydrocarbon composition is derived from a decade of Cassini Composite Infrared Spectrometer (CIRS) 7-16 $mu$m thermal infrared spectroscopy. We construct a near-continuous record of
atmospheric variability poleward of 60$^circ$ from northern winter/southern summer (2004, $L_s=293^circ$) through the equinox (2009, $L_s=0^circ$) to northern spring/southern autumn (2014, $L_s=56^circ$). The hot tropospheric polar cyclones and the hexagonal shape of the north polar belt are both persistent features throughout the decade of observations. The hexagon vertices rotated westward by $approx30^circ$ longitude between March 2007 and April 2013, confirming that they are not stationary in the Voyager-defined System III longitude system as previously thought. The extended region of south polar stratospheric emission has cooled dramatically poleward of the sharp temperature gradient near 75$^circ$S, coinciding with a depletion in the abundances of acetylene and ethane, and suggestive of stratospheric upwelling with vertical wind speeds of $wapprox+0.1$ mm/s. This is mirrored by a general warming of the northern polar stratosphere and an enhancement in acetylene and ethane abundances that appears to be most intense poleward of 75$^circ$N, suggesting subsidence at $wapprox-0.15$ mm/s. However, the sharp gradient in stratospheric emission expected to form near 75$^circ$N by northern summer solstice (2017, $L_s=90^circ$) has not yet been observed, so we continue to await the development of a northern summer stratospheric vortex. North polar minima in tropospheric and stratospheric temperatures were detected in 2008-2010 (lagging one season, or 6-8 years, behind winter solstice); south polar maxima appear to have occurred before the start of the Cassini observations (1-2 years after summer solstice). [Abridged]
On 2007 December 16-17, spectra were acquired of the disk of Uranus by the Spitzer Infrared Spectrometer (IRS) when its equator was close to the sub-earth point. This spectrum provides the highest-resolution broad-band spectrum ever obtained for Uran
us from space, allowing a determination of the disk-averaged temperature and molecule composition to a greater degree of accuracy than ever before. The temperature profiles derived from the Voyager radio occultation experiments that match these data best are those that assume a high abundance of methane in the deep atmosphere, but none of these models provides a satisfactory fit over the full spectral range. This be the result of spatial differences between global and low-latitudinal regions, changes in time, missing continuum opacity sources such as stratospheric hazes or unknown tropospheric constituents, or undiagnosed systematic problems with either the radio-occultation or the Spitzer IRS data sets. The spectrum is compatible with the stratospheric temperatures derived from the Voyager ultraviolet occultations measurements. Thermospheric temperatures determined from the analysis of the observed H2 quadrupole emission features are colder than those derived by Herbert et al. at pressures less than ~1 microbar. Extrapolation of the nominal model spectrum to far-infrared through millimeter wavelengths shows that the spectrum arising solely from H2 collision-induced absorption is too warm to reproduce observations between wavelengths of 0.8 and 3.3 mm. Adding an additional absorber such as H2S provides a reasonable match to the spectrum, although a unique identification of the responsible absorber is not yet possible with available data. An immediate practical use for the spectrum resulting from this model is to establish a high-precision continuum flux model for use as an absolute radiometric standard for future astronomical observations.
Mid-infrared spectral observations Uranus acquired with the Infrared Spectrometer (IRS) on the Spitzer Space Telescope are used to determine the abundances of C2H2, C2H6, CH3C2H, C4H2, CO2, and tentatively CH3 on Uranus at the time of the 2007 equino
x. For vertically uniform eddy diffusion coefficients in the range 2200-2600 cm2 s-1, photochemical models that reproduce the observed methane emission also predict C2H6 profiles that compare well with emission in the 11.6-12.5 micron wavelength region, where the nu9 band of C2H6 is prominent. Our nominal model with a uniform eddy diffusion coefficient Kzz = 2430 cm2 sec-1 and a CH4 tropopause mole fraction of 1.6x10-5 provides a good fit to other hydrocarbon emission features, such as those of C2H2 and C4H2, but the model profile for CH3C2H must be scaled by a factor of 0.43, suggesting that improvements are needed in the chemical reaction mechanism for C3Hx species. The nominal model is consistent with a CH3D/CH4 ratio of 3.0+-0.2x10-4. From the best-fit scaling of these photochemical-model profiles, we derive column abundances above the 10-mbar level of 4.5+01.1/-0.8 x 10+19 molecule-cm-2 for CH4, 6.2 +- 1.0 x 10+16 molecule-cm-2 for C2H2 (with a value 24% higher from a different longitudinal sampling), 3.1 +- 0.3 x 10+16 molecule-cm-2 for C2H6, 8.6 +- 2.6 x 10+13 molecule-cm-2 for CH3C2H, 1.8 +- 0.3 x 10+13 molecule-cm-2 for C4H2, and 1.7 +- 0.4 x 10+13 molecule-cm-2 for CO2 on Uranus. Our results have implications with respect to the influx rate of exogenic oxygen species and the production rate of stratospheric hazes on Uranus, as well as the C4H2 vapor pressure over C4H2 ice at low temperatures.
Imaging and spectroscopy of Neptunes thermal infrared emission is used to assess seasonal changes in Neptunes zonal mean temperatures between Voyager-2 observations (1989, heliocentric longitude Ls=236) and southern summer solstice (2005, Ls=270). Ou
r aim was to analyse imaging and spectroscopy from multiple different sources using a single self-consistent radiative-transfer model to assess the magnitude of seasonal variability. Globally-averaged stratospheric temperatures measured from methane emission tend towards a quasi-isothermal structure (158-164 K) above the 0.1-mbar level, and are found to be consistent with spacecraft observations of AKARI. This remarkable consistency, despite very different observing conditions, suggests that stratospheric temporal variability, if present, is $pm$5 K at 1 mbar and $pm$3 K at 0.1 mbar during this solstice period. Conversely, ethane emission is highly variable, with abundance determinations varying by more than a factor of two. The retrieved C2H6 abundances are extremely sensitive to the details of the T(p) derivation. Stratospheric temperatures and ethane are found to be latitudinally uniform away from the south pole (assuming a latitudinally-uniform distribution of stratospheric methane). At low and midlatitudes, comparisons of synthetic Voyager-era images with solstice-era observations suggest that tropospheric zonal temperatures are unchanged since the Voyager 2 encounter, with cool mid-latitudes and a warm equator and pole. A re-analysis of Voyager/IRIS 25-50 {mu}m mapping of tropospheric temperatures and para-hydrogen disequilibrium suggests a symmetric meridional circulation with cold air rising at mid-latitudes (sub-equilibrium para-H2 conditions) and warm air sinking at the equator and poles (super-equilibrium para-H2 conditions). The most significant atmospheric changes are associated with the polar vortex (absent in 1989).
