Context: ALMA observations of Venus at 267 GHz have been presented in the literature that show the apparent presence of phosphine (PH3) in its atmosphere. Phosphine has currently no evident production routes on the planets surface or in its atmospher
e. Aims: The aim of this work is to assess the statistical reliability of the line detection by independent re-analysis of the ALMA data. Methods: The ALMA data were reduced as in the published study, following the provided scripts. First the spectral analysis presented in the study was reproduced and assessed. Subsequently, the spectrum was statistically evaluated, including its dependence on selected ALMA baselines. Results: We find that the 12th-order polynomial fit to the spectral passband utilised in the published study leads to spurious results. Following their recipe, five other >10 sigma lines can be produced in absorption or emission within 60 km/s from the PH3 1-0 transition frequency by suppressing the surrounding noise. Our independent analysis shows a feature near the PH3 frequency at a ~2 sigma level, below the common threshold for statistical significance. Since the spectral data have a non-Gaussian distribution, we consider a feature at such level as statistically unreliable that cannot be linked to a false positive probability. Conclusions: We find that the published 267-GHz ALMA data provide no statistical evidence for phosphine in the atmosphere of Venus.
Context. Observations of molecular gas have played a key role in developing the current understanding of the late stages of stellar evolution. Aims. The survey Planetary nebulae AND their cO Reservoir with APEX (PANDORA) was designed to study the cir
cumstellar shells of evolved stars with the aim to estimate their physical parameters. Methods. Millimetre carbon monoxide (CO) emission is the most useful probe of the warm molecular component ejected by low- to intermediate-mass stars. CO is the second-most abundant molecule in the Universe, and the millimeter transitions are easily excited, thus making it particularly useful to study the mass, structure, and kinematics of the molecular gas. We present a large survey of the CO (J = 3 - 2) line using the Atacama Pathfinder EXperiment (APEX) telescope in a sample of 93 proto-planetary nebulae and planetary nebulae. Results. CO (J = 3 - 2) was detected in 21 of the 93 objects. Conclusions. CO (J = 3 - 2) was detected in all 4 observed pPNe (100%), 15 of the 75 PNe (20%), one of the 4 wide binaries (25%), and in 1 of the 10 close binaries (10%). Using the CO (J = 3 - 2) line, we estimated the column density and mass of each source.
Extremely high velocity emission likely related to jets is known to occur in some proto-Planetary Nebulae. However, the molecular complexity of this kinematic component is largely unknown. We observed the known extreme outflow from the proto-Planetar
y Nebula IRAS 16342-3814, a prototype water fountain, in the full frequency range from 73 to 111 GHz with the RSR receiver on the Large Millimetre Telescope. We detected the molecules SiO, HCN, SO, and $^{13}$CO. All molecular transitions, with the exception of the latter are detected for the first time in this source, and all present emission with velocities up to a few hundred km s$^{-1}$. IRAS 16342-3814 is therefore the only source of this kind presenting extreme outflow activity simultaneously in all these molecules, with SO and SiO emission showing the highest velocities found of these species in proto-Planetary Nebulae. To be confirmed is a tentative weak SO component with a FWHM $sim$ 700 km s$^{-1}$. The extreme outflow gas consists of dense gas (n$_{rm H_2} >$ 10$^{4.8}$--10$^{5.7}$ cm$^{-3}$), with a mass larger than $sim$ 0.02--0.15 M$_{odot}$. The relatively high abundances of SiO and SO may be an indication of an oxygen-rich extreme high velocity gas.
During the late stages of their evolution, Sun-like stars bring the products of nuclear burning to the surface. Most of the carbon in the Universe is believed to originate from stars with masses up to a few solar masses. Although there is a chemical
dichotomy between oxygen-rich and carbon-rich evolved stars, the dredge-up itself has never been directly observed. In the last three decades, however, a few stars have been shown to display both carbon- and oxygen-rich material in their circumstellar envelopes. Two models have been proposed to explain this dual chemistry: one postulates that a recent dredge-up of carbon produced by nucleosynthesis inside the star during the Asymptotic Giant Branch changed the surface chemistry of the star. The other model postulates that oxygen-rich material exists in stable keplerian rotation around the central star. The two models make contradictory, testable, predictions on the location of the oxygen-rich material, either located further from the star than the carbon-rich gas, or very close to the star in a stable disk. Using the Faint Object InfraRed CAmera (FORCAST) instrument on board the Stratospheric Observatory for Infrared Astronomy (SOFIA) Telescope, we obtained images of the carbon-rich planetary nebula (PN) BD+30 3639 which trace both carbon-rich polycyclic aromatic hydrocarbons (PAHs) and oxygen-rich silicate dust. With the superior spectral coverage of SOFIA, and using a 3D photoionisation and dust radiative transfer model we prove that the O-rich material is distributed in a shell in the outer parts of the nebula, while the C-rich material is located in the inner parts of the nebula. These observations combined with the model, suggest a recent change in stellar surface composition for the double chemistry in this object. This is evidence for dredge-up occurring ~1000yr ago.
