All-optical addressing and control of single solid-state based qubits allows for scalable architectures of quantum devices such as quantum networks and quantum simulators. So far, all-optical addressing of qubits was demonstrated only for color cente
rs in diamond and quantum dots. Here, we demonstrate generation of coherent dark state of a single rare earth ion in a solid, namely a cerium ion in yttrium aluminum garnet (YAG). The dark state was formed under the condition of coherent population trapping. Furthermore, high-resolution spectroscopic studies of native and implanted single Ce ions have been performed. They revealed narrow and spectrally stable optical transitions between the spin sublevels of the ground and excited optical states, indicating the feasibility of interfacing single photons with a single electron spin of a cerium ion.
