Atomic and Molecular Systems Driven by Intense Chaotic Light

We investigate dynamics of atomic and molecular systems exposed to intense, shaped chaotic fields and a weak femtosecond laser pulse theoretically. As a prototype example, the photoionization of a hydrogen atom is considered in detail. The net photoionization undergoes an optimal enhancement when a broadband chaotic field is added to the weak laser pulse. The enhanced ionization is analyzed using time-resolved wavepacket evolution and the population dynamics of the atomic levels. We elucidate the enhancement produced by spectrally-shaped chaotic fields of two different classes, one with a tunable bandwidth and another with a narrow bandwidth centered at the first atomic transition. Motivated by the large bandwidth provided in the high harmonic generation, we also demonstrate the enhancement effect exploiting chaotic fields synthesized from discrete, phase randomized, odd-order and all-order high harmonics of the driving pulse. These findings are generic and can have applications to other atomic and simple molecular systems.

Femtosecond Photoionization of Atoms under Noise

We investigate the effect of incoherent perturbations on atomic photoionization due to a femtosecond mid-infrared laser pulse by solving the time-dependent stochastic Schrodinger equation. For a weak laser pulse which causes almost no ionization, an addition of a Gaussian white noise to the pulse leads to a significantly enhanced ionization probability. Tuning the noise level, a stochastic resonance-like curve is observed showing the existence of an optimum noise for a given laser pulse. Besides studying the sensitivity of the obtained enhancement curve on the pulse parameters, such as the pulse duration and peak amplitude, we suggest that experimentally realizable broadband chaotic light can also be used instead of the white noise to observe similar features. The underlying enhancement mechanism is analyzed in the frequency-domain by computing a frequency-resolved atomic gain profile, as well as in the time-domain by controlling the relative delay between the action of the laser pulse and noise.