High-Q microwave cavity modes coupled to transmon ancillas provide a hardware-efficient platform for quantum computing. Due to their coupling, the cavity modes inherit finite nonlinearity from the transmons. In this work, we theoretically and experim
entally investigate how an off-resonant drive on the transmon ancilla modifies the nonlinearities of cavity modes in qualitatively different ways, depending on the interrelation among cavity-transmon detuning, drive-transmon detuning and transmon anharmonicity. For a cavity-transmon detuning that is smaller than or comparable to the drive-transmon detuning and transmon anharmonicity, the off-resonant transmon drive can induce multiphoton resonances among cavity and transmon excitations that strongly modify cavity nonlinearities as drive parameters vary. For a large cavity-transmon detuning, the drive induces cavity-photon-number-dependent ac Stark shifts of transmon levels that translate into effective cavity nonlinearities. In the regime of weak transmon-cavity coupling, the cavity Kerr nonlinearity relates to the third-order nonlinear susceptibility function $chi^{(3)}$ of the driven ancilla. This susceptibility function provides a numerically efficient way of computing the cavity Kerr particularly for systems with many cavity modes controlled by a single transmon. It also serves as a diagnostic tool for identifying undesired drive-induced multiphoton resonance processes. Lastly, we show that by judiciously choosing the drive amplitude, a single off-resonant transmon drive can be used to cancel the cavity self-Kerr nonlinearity or the inter-cavity cross-Kerr. This provides a way of dynamically correcting the cavity Kerr nonlinearity during bosonic operations or quantum error correction protocols that rely on the cavity modes being linear.
Single-photon detectors are ubiquitous and integral components of photonic quantum cryptography, communication, and computation. Many applications, however, require not only detecting the presence of any photons, but distinguishing the number present
with a single shot. Here, we implement a single-shot, high-fidelity photon number-resolving detector of up to 15 microwave photons in a cavity-qubit circuit QED platform. This detector functions by measuring a series of generalized parity operators which make up the bits in the binary decomposition of the photon number. Our protocol consists of successive, independent measurements of each bit by entangling the ancilla with the cavity, then reading out and resetting the ancilla. Photon loss and ancilla readout errors can flip one or more bits, causing nontrivial errors in the outcome, but these errors have a traceable form which can be captured in a simple hidden Markov model. Relying on the independence of each bit measurement, we mitigate biases in ensembles of measurements, showing good agreement with the predictions of the model. The mitigation improves the average total variation distance error of Fock states from $13.5%$ to $1.1%$. We also show that the mitigation is efficiently scalable to an $M$-mode system provided that the errors are independent and sufficiently small. Our work motivates the development of new algorithms that utilize single-shot, high-fidelity PNR detectors.
The efficient simulation of quantum systems is a primary motivating factor for developing controllable quantum machines. For addressing systems with underlying bosonic structure, it is advantageous to utilize a naturally bosonic platform. Optical pho
tons passing through linear networks may be configured to perform quantum simulation tasks, but the efficient preparation and detection of multiphoton quantum states of light in linear optical systems are challenging. Here, we experimentally implement a boson sampling protocol for simulating molecular vibronic spectra [Nature Photonics $textbf{9}$, 615 (2015)] in a two-mode superconducting device. In addition to enacting the requisite set of Gaussian operations across both modes, we fulfill the scalability requirement by demonstrating, for the first time in any platform, a high-fidelity single-shot photon number resolving detection scheme capable of resolving up to 15 photons per mode. Furthermore, we exercise the capability of synthesizing non-Gaussian input states to simulate spectra of molecular ensembles in vibrational excited states. We show the re-programmability of our implementation by extracting the spectra of photoelectron processes in H$_2$O, O$_3$, NO$_2$, and SO$_2$. The capabilities highlighted in this work establish the superconducting architecture as a promising platform for bosonic simulations, and by combining them with tools such as Kerr interactions and engineered dissipation, enable the simulation of a wider class of bosonic systems.
