We consider the deposition of a film of viscous liquid on a flat plate being withdrawn from a bath, experimentally and theoretically. For any plate speed $U$, there is a range of ``thick film solutions whose thickness scales like $U^{1/2}$ for small
$U$. These solutions are realized for a partially wetting liquid, while for a perfectly wetting liquid the classical Landau-Levich-Derjaguin (LLD) film is observed, whose thickness scales like $U^{2/3}$. The thick film is distinguished from the LLD film by a dip in its spatial profile at the transition to the bath. We calculate the phase diagram for the existence of stationary film solutions as well as the film profiles, and find excellent agreement with experiment.
When a solid plate is withdrawn from a liquid bath, a receding contact line is formed where solid, liquid, and gas meet. Above a critical speed $U_{cr}$, a stationary contact line can no longer exist and the solid will eventually be covered completel
y by a liquid film. Here we show that the bifurcation diagram of this coating transition changes qualitatively, from discontinuous to continuous, when decreasing the inclination angle of the plate. We show that this effect is governed by the presence of capillary waves, illustrating that the large scale flow strongly effects the maximum speed of dewetting.
The dynamics of receding contact lines is investigated experimentally through controlled perturbations of a meniscus in a dip coating experiment. We first characterize stationary menisci and their breakdown at the coating transition. It is then shown
that the dynamics of both liquid deposition and long-wavelength perturbations adiabatically follow these stationary states. This provides a first experimental access to the entire bifurcation diagram of dynamical wetting, confirming the hydrodynamic theory developed in Part 1. In contrast to quasi-static theories based on a dynamic contact angle, we demonstrate that the transition strongly depends on the large scale flow geometry. We then establish the dispersion relation for large wavenumbers, for which we find that sigma is linear in q. The speed dependence of sigma is well described by hydrodynamic theory, in particular the absence of diverging time-scales at the critical point. Finally, we highlight some open problems related to contact angle hysteresis that lead beyond the current description.
The relaxation of a dewetting contact line is investigated theoretically in the so-called Landau-Levich geometry in which a vertical solid plate is withdrawn from a bath of partially wetting liquid. The study is performed in the framework of lubricat
ion theory, in which the hydrodynamics is resolved at all length scales (from molecular to macroscopic). We investigate the bifurcation diagram for unperturbed contact lines, which turns out to be more complex than expected from simplified quasi-static theories based upon an apparent contact angle. Linear stability analysis reveals that below the critical capillary number of entrainment, Ca_c, the contact line is linearly stable at all wavenumbers. Away from the critical point the dispersion relation has an asymptotic behaviour sigma~|q| and compares well to a quasi-static approach. Approaching Ca_c, however, a different mechanism takes over and the dispersion evolves from |q| to the more common q^2. These findings imply that contact lines can not be treated as universal objects governed by some effective law for the macroscopic contact angle, but viscous effects have to be treated explicitly.
