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We show that the equations underlying the $GW$ approximation have a large number of solutions. This raises the question: which is the physical solution? We provide two theorems which explain why the methods currently in use do, in fact, find the corr ect solution. These theorems are general enough to cover a large class of similar algorithms. An efficient algorithm for including self-consistent vertex corrections well beyond $GW$ is also described and further used in numerical validation of the two theorems.
We study the graphite intercalated compound CaC$_6$ by means of Eliashberg theory, focusing on the anisotropy properties. An analysis of the electron-phonon coupling is performed, and we define a minimal 6-band anisotropy structure. Comparing with Su perconducting Density Functional Theory (SCDFT) the condition under which Eliashberg theory is able to reproduce the SCDFT gap structure is determined, and we discuss the role of Coulomb interactions. The Engelsberg-Schrieffer polaron structure is computed by solving the Eliashberg equation on the Matsubara axis and analytically continuing it to the full complex plane. This reveals the polaronic quasiparticle bands anisotropic features as well as the interplay with superconductivity.
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