Detection of chloronium and measurement of the 35Cl/37Cl isotopic ratio at z=0.89 toward PKS1830-211

We report the first extragalactic detection of chloronium (H2Cl+), in the z=0.89 absorber in front of the lensed blazar PKS1830-211. The ion is detected through its 1_11-0_00 line along two independent lines of sight toward the North-East and South-West images of the blazar. The relative abundance of H2Cl+ is significantly higher (by a factor ~7) in the NE line of sight, which has a lower H2/H fraction, indicating that H2Cl+ preferably traces the diffuse gas component. From the ratio of the H2^35Cl+ and H2^37Cl+ absorptions toward the SW image, we measure a 35Cl/37Cl isotopic ratio of 3.1 (-0.2; +0.3) at z=0.89, similar to that observed in the Galaxy and the solar system.

A precise and accurate determination of the cosmic microwave background temperature at z=0.89

According to the Big Bang theory and as a consequence of adiabatic expansion of the Universe, the temperature of the cosmic microwave background (CMB) increases linearly with redshift. This relation is, however, poorly explored, and detection of any deviation would directly lead to (astro-)physics beyond the standard model. We aim at measuring the temperature of the CMB with an accuracy of a few percent at z=0.89 toward the molecular absorber in the galaxy lensing the quasar PKS1830-211. We adopt a Monte-Carlo Markov Chain approach, coupled with predictions from the non-LTE radiative transfer code RADEX, to solve the excitation of a set of various molecular species directly from their spectra. We determine Tcmb=5.08 pm 0.10 K at 68% confidence level. Our measurement is consistent with the value Tcmb=5.14 K predicted by the standard cosmological model with adiabatic expansion of the Universe. This is the most precise determination of Tcmb at z>0 to date.

Ground-state ammonia and water in absorption towards Sgr B2

We have used the Odin submillimetre-wave satellite telescope to observe the ground state transitions of ortho-ammonia and ortho-water, including their 15N, 18O, and 17O isotopologues, towards Sgr B2. The extensive simultaneous velocity coverage of the observations, >500 km/s, ensures that we can probe the conditions of both the warm, dense gas of the molecular cloud Sgr B2 near the Galactic centre, and the more diffuse gas in the Galactic disk clouds along the line-of-sight. We present ground-state NH3 absorption in seven distinct velocity features along the line-of-sight towards Sgr B2. We find a nearly linear correlation between the column densities of NH3 and CS, and a square-root relation to N2H+. The ammonia abundance in these diffuse Galactic disk clouds is estimated to be about (0.5-1)e-8, similar to that observed for diffuse clouds in the outer Galaxy. On the basis of the detection of H218O absorption in the 3 kpc arm, and the absence of such a feature in the H217O spectrum, we conclude that the water abundance is around 1e-7, compared to ~1e-8 for NH3. The Sgr B2 molecular cloud itself is seen in absorption in NH3, 15NH3, H2O, H218O, and H217O, with emission superimposed on the absorption in the main isotopologues. The non-LTE excitation of NH3 in the environment of Sgr B2 can be explained without invoking an unusually hot (500 K) molecular layer. A hot layer is similarly not required to explain the line profiles of the 1_{1,0}-1_{0,1} transition from H2O and its isotopologues. The relatively weak 15NH3 absorption in the Sgr B2 molecular cloud indicates a high [14N/15N] isotopic ratio >600. The abundance ratio of H218O and H217O is found to be relatively low, 2.5--3. These results together indicate that the dominant nucleosynthesis process in the Galactic centre is CNO hydrogen burning.