Quantum Plasmonics: Nonlocal effects in coupled nanowire dimer

The optical response of a coupled nanowire dimer is studied using a fully quantum mechanical approach. The translational invariance of the system allows to apply the time--dependent density functional theory for the plasmonic dimer with the largest size considered so far in quantum calculations. Detailed comparisons with results from classical electromagnetic calculations based on local and non local hydrodynamic response, as well as with results of the recently developed quantum corrected model is performed. We show that electron tunneling and dynamical screening are the major nonlocal quantum effects determining the plasmonic modes and field enhancement in the system. Account for the electron tunneling at small junction sizes allows semi-quantitative description of quantum results within classical framework. We also discuss the shortcomings of classical treatments using non-local dielectric permittivities based on hydrodynamic models. Finally, the implications of the actual position of the screening charge density for the plasmon ruler applications are demonstrated.

Plasmons in nearly touching metallic nanoparticles: singular response in the limit of touching dimers

The response of gold nanoparticle dimers is studied theoretically near and beyond the limit where the particles are touching. As the particles approach each other, a dominant dipole feature is observed that is pushed into the infrared due to interparticle coupling and that is associated with a large pileup of induced charge in the interparticle gap. The redshift becomes singular as the particle separation decreases. The response weakens for very small separation when the coupling across the interparticle gap becomes so strong that dipolar oscillations across the pair are inhibited. Lower-wavelength, higher-order modes show a similar separation dependence in nearly touching dimers. After touching, singular behavior is observed through the emergence of a new infrared absorption peak, also accompanied by huge charge pileup at the interparticle junction, if initial interparticle-contact is made at a single point. This new mode is distinctly different from the lowest mode of the separated dimer. When the junction is made by contact between flat surfaces, charge at the junction is neutralized and mode evolution is continuous through contact. The calculated singular response explains recent experiments on metallic nanoparticle dimers and is relevant in the design of nanoparticle-based sensors and plasmon circuits.