An analysis of high-resolution near-infrared spectra of a sample of 45 asymptotic giant branch (AGB) stars towards the Galactic bulge is presented. The sample consists of two subsamples, a larger one in the inner and intermediate bulge, and a smaller
one in the outer bulge. The data are analysed with the help of hydrostatic model atmospheres and spectral synthesis. We derive the radial velocity of all stars, and the atmospheric chemical mix ([Fe/H], C/O, $^{12}$C/$^{13}$C, Al, Si, Ti, and Y) where possible. Our ability to model the spectra is mainly limited by the (in)completeness of atomic and molecular line lists, at least for temperatures down to $T_{rm eff}approx3100$ K. We find that the subsample in the inner and intermediate bulge is quite homogeneous, with a slightly sub-solar mean metallicity and only few stars with super-solar metallicity, in agreement with previous studies of non-variable M-type giants in the bulge. All sample stars are oxygen-rich, C/O$<$1.0. The C/O and carbon isotopic ratios suggest that third dredge-up (3DUP) is absent among the sample stars, except for two stars in the outer bulge that are known to contain technetium. These stars are also more metal-poor than the stars in the intermediate or inner bulge. Current stellar masses are determined from linear pulsation models. The masses, metallicities and 3DUP behaviour are compared to AGB evolutionary models. We conclude that these models are partly in conflict with our observations. Furthermore, we conclude that the stars in the inner and intermediate bulge belong to a more metal-rich population that follows bar-like kinematics, whereas the stars in the outer bulge belong to the metal-poor, spheroidal bulge population.
S-type AGB stars are thought to be in the transitional phase between M-type and C-type AGB stars. Because of their peculiar chemical composition, one may expect a strong influence of the stellar C/O ratio on the molecular chemistry and the mineralogy
of the circumstellar dust. In this paper, we present a large sample of 87 intrinsic galactic S-type AGB stars, observed at infrared wavelengths with the Spitzer Space Telescope, and supplemented with ground-based optical data. On the one hand, we derive the stellar parameters from the optical spectroscopy and photometry, using a grid of model atmospheres. On the other, we decompose the infrared spectra to quantify the flux-contributions from the different dust species. Finally, we compare the independently determined stellar parameters and dust properties. For the stars without significant dust emission, we detect a strict relation between the presence of SiS absorption in the Spitzer spectra and the C/O ratio of the stellar atmosphere. These absorption bands can thus be used as an additional diagnostic for the C/O ratio. For stars with significant dust emission, we define three groups, based on the relative contribution of certain dust species to the infrared flux. We find a strong link between group-membership and C/O ratio. We show that these groups can be explained by assuming that the dust-condensation can be cut short before silicates are produced, while the remaining free atoms and molecules can then form the observed magnesium sulfides or the carriers of the unidentified 13 and 20 micron features. Finally, we present the detection of emission features attributed to molecules and dust characteristic to C-type stars, such as molecular SiS, hydrocarbons and magnesium sulfide grains. We show that we often detect magnesium sulfides together with molecular SiS and we propose that it is formed by a reaction of SiS molecules with Mg.
Asymptotic Giant Branch variables are found to obey period-luminosity relations in the mid-IR similar to those seen at K_S (2.14 microns), even at 24 microns where emission from circumstellar dust is expected to be dominant. Their loci in the M, logP
diagrams are essentially the same for the LMC and for NGC6522 in spite of different ages and metallicities. There is no systematic trend of slope with wavelength. The offsets of the apparent magnitude vs. logP relations imply a difference between the two fields of 3.8 in distance modulus. The colours of the variables confirm that a principal period with log P > 1.75 is a necessary condition for detectable mass-loss. At the longest observed wavelength, 24 microns, many semi-regular variables have dust shells comparable in luminosity to those around Miras. There is a clear bifurcation in LMC colour-magnitude diagrams involving 24 micron magnitudes.
