We seek for the optimal strategy to infer the width $a$ of an infinite potential wells by performing measurements on the particle(s) contained in the well. In particular, we address quantum estimation theory as the proper framework to formulate the p
roblem and find the optimal quantum measurement, as well as to evaluate the ultimate bounds to precision. Our results show that in a static framework the best strategy is to measure position on a delocalized particle, corresponding to a width-independent quantum signal-to-noise ratio (QSNR), which increases with delocalisation. Upon considering time-evolution inside the well, we find that QSNR increases as $t^2$. On the other hand, it decreases with $a$ and thus time-evolution is a metrological resource only when the width is not too large compared to the available time evolution. Finally, we consider entangled probes placed into the well and observe super-additivity of the QSNR: it is the sum of the single-particle QSNRs, plus a positive definite term, which depends on their preparation and may increase with the number of entangled particles. Overall, entanglement represents a resource for the precise characterization of potential wells.
