Many of the electronic properties of high-temperature cuprate superconductors (HTSC) are strongly dependent on the number of charge carriers put into the CuO$_2$ planes (doping). Superconductivity appears over a dome-shaped region of the doping-tempe
rature phase diagram. The highest critical temperature (Tc) is obtained for the so-called optimum doping. The doping mechanism is usually chemical; it can be done by cationic substitution. This is the case, for example, in La$_{2-x}$Sr$_x$CuO$_4$ where La3+ is replaced by Sr2+ thus adding a hole to the CuO$_2$ planes. A similar effect is achieved by adding oxygen as in the case of YBa$_2$Cu$_3$O$_{6+delta}$ where $delta$ represents the excess oxygen in the sample. In this paper we report on a different mechanism, one that enables the addition or removal of carriers from the surface of the HTSC. This method utilizes a self-assembled monolayer (SAM) of polar molecules adsorbed on the cuprate surface. In the case of optically active molecules, the polarity of the SAM can be modulated by shining light on the coated surface. This results in a light-induced modulation of the superconducting phase transition of the sample. The ability to control the superconducting transition temperature with the use of SAMs makes these surfaces practical for various devices such as switches and detectors based on high-Tc superconductors.
Manipulation of light-beams with subwavelenth metallic devices has motivated intensive studies, following the discovery of extraordinary transmission of electromagnetic waves through sub-wavelength apertures in thin noble-metal films. The propagation
of light in these holes can be investigated at greately improved spatial resolution by means of focused electron-beams. Here we demonstrate direct e-beam excitation of radiative cavity modes well below the surface plasmon (SP) frequency, of isolated rectangular holes in gold films, illuminating the hotly debated phenomenon of the extraordinary optical transmission through subwavelength holes. The exceptionally long range e-beam interaction with the metal through the vacuum, involving electromagnetic excitations within the light cone, is allowed by momentum conservation breakdown along the e-beam axis. Two types of lowlying excited modes are revealed: radiative cavity modes which are nearly unaffected by SPs, and SP polariton modes with waveguide character in the near field region of the slit walls, which in spite of the strong hybridization preserve the waveguide cutoff frequencies and symmetry characteristics.
We investigate the photoconductance of single-walled carbon nanotube-nanocrystalhybrids. The nanocrystals are bound to the nanotubes via molecular recognition. We find that the photoconductance of the hybrids can be adjusted by the absorption charact
eristics of the nanocrystals. In addition, the photoconductance of the hybrids surprisingly exhibits a slow time constant of about 1 ms after excitation of the nanocrystals. The data are consistent with a bolometrically induced current increase in the nanotubes caused by photon absorption in the nanocrystals.
