We exploit the impact of exact frequency modulation on transition time of steering nuclear spin states from theoretical point of view. 1-stage and 2-stage Frequency-Amplitude-Phase modulation (FAPM) algorithms are proposed in contrast with 1-stage an
d 3-stage Amplitude-Phase modulation (APM) algorithms. The sufficient conditions are further present for transiting nuclear spin states within the specified time by these four modulation algorithms. It is demonstrated that transition time performance can be significantly improved if exact frequency modulation is available. It is exemplified that the transition time scale with frequency modulation is about 1/4 of that without frequency modulation. It is also revealed in this research that the hybrid scheme of 1-stage FAPM and APM algorithms is better than all the four modulation algorithms. A simplified hybrid modulation algorithm is also proposed to reduce computational burden.
