Although the fully connected Ising model does not have a length scale, we show that its critical exponents can be found using finite size scaling with the scaling variable equal to N, the number of spins. We find that at the critical temperature of t
he infinite system the mean value and the most probable value of the magnetization scale differently with N, and the probability distribution of the magnetization is not a Gaussian, even for large N. Similar results inconsistent with the usual understanding of mean-field theory are found at the spinodal. We relate these results to the breakdown of hyperscaling and show how hyperscaling can be restored by increasing N while holding the Ginzburg parameter rather than the temperature fixed.
We investigate the approach to stable and metastable equilibrium in Ising models using a cluster representation. The distribution of nucleation times is determined using the Metropolis algorithm and the corresponding $phi^{4}$ model using Langevin dy
namics. We find that the nucleation rate is suppressed at early times even after global variables such as the magnetization and energy have apparently reached their time independent values. The mean number of clusters whose size is comparable to the size of the nucleating droplet becomes time independent at about the same time that the nucleation rate reaches its constant value. We also find subtle structural differences between the nucleating droplets formed before and after apparent metastable equilibrium has been established.
The homogeneous and heterogeneous nucleation of a Lennard-Jones liquid is investigated using the umbrella sampling method. The free energy cost of forming a nucleating droplet is determined as a function of the quench depth, and the saddle point natu
re of the droplets is verified using an intervention technique. The structure and symmetry of the nucleating droplets is found for a range of temperatures. We find that for deep quenches the nucleating droplets become more anisotropic and diffuse with no well defined core or surface. The environment of the nucleating droplets form randomly stacked hexagonal planes. This behavior is consistent with a spinodal nucleation interpretation. We also find that the free energy barrier for heterogeneous nucleation is a minimum when the lattice spacing of the impurity equals the lattice spacing of the equilibrium crystalline phase. If the lattice spacing of the impurity is different, the crystal grows into the bulk instead of wetting the impurity.
