We describe a high-resolution spectroscopy method, in which the detection of single excitation events is enhanced by a complete loss of coherence of a superposition of two ground states. Thereby, transitions of a single isolated atom nearly at rest a
re recorded efficiently with high signal-to-noise ratios. Spectra display symmetric line shapes without stray-light background from spectroscopy probes. We employ this method on a $^{25}$Mg$^+$ ion to measure one, two, and three-photon transition frequencies from the 3S ground state to the 3P, 3D, and 4P excited states, respectively. Our results are relevant for astrophysics and searches for drifts of fundamental constants. Furthermore, the method can be extended to other transitions, isotopes, and species. The currently achieved fractional frequency uncertainty of $5 times 10^{-9}$ is not limited by the method.
Employing a recently proposed measure for quantum non-Markovianity, we carry out a systematic study of the size of memory effects in the spin-boson model for a large region of temperature and frequency cutoff parameters. The dynamics of the open syst
em is described utilizing a second-order time-convolutionless master equation without the Markov or rotating wave approximations. While the dynamics is found to be strongly non-Markovian for low temperatures and cutoffs, in general, we observe a special regime favoring Markovian behavior. This effect is explained as resulting from a resonance between the systems transition frequency and the frequencies of the dominant environmental modes. We further demonstrate that the corresponding Redfield equation is capable of reproducing the characteristic features of the non-Markovian quantum behavior of the model.
