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The presence of multiple populations in globular clusters has been well established thanks to high-resolution spectroscopy. It is widely accepted that distinct populations are a consequence of different stellar generations: intra-cluster pollution ep isodes are required to produce the peculiar chemistry observed in almost all clusters. Unfortunately, the progenitors responsible have left an ambiguous signature and their nature remains unresolved. To constrain the candidate polluters, we have measured lithium and aluminium abundances in more than 180 giants across three systems: NGC~1904, NGC~2808, and NGC~362. The present investigation along with our previous analysis of M12 and M5 affords us the largest database of simultaneous determinations of Li and Al abundances. Our results indicate that Li production has occurred in each of the three clusters. In NGC~362 we detected an M12-like behaviour, with first and second-generation stars sharing very similar Li abundances favouring a progenitor that is able to produce Li, such as AGB stars. Multiple progenitor types are possible in NGC~1904 and NGC~2808, as they possess both an intermediate population comparable in lithium to the first generation stars and also an extreme population, that is enriched in Al but depleted in Li. A simple dilution model fails in reproducing this complex pattern. Finally, the internal Li variation seems to suggest that the production efficiency of this element is a function of the clusters mass and metallicity - low-mass or relatively metal-rich clusters are more adept at producing Li.
We provide a brief review of thermohaline physics and why it is a candidate extra mixing mechanism during the red giant branch (RGB). We discuss how thermohaline mixing (also called $delta$ $mu$ mixing) during the RGB due to helium-3 burning, is more complicated than the operation of thermohaline mixing in other stellar contexts (such as following accretion from a binary companion). We try to use observations of carbon depletion in globular clusters to help constrain the formalism and the diffusion coefficient or mixing velocity that should be used in stellar models. We are able to match the spread of carbon depletion for metal poor field giants but are unable to do so for cluster giants, which may show evidence of mixing prior to even the first dredge-up event.
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