An ever growing number of observational and theoretical evidence suggests that the deuterated fraction (column density ratio between a species containing D and its hydrogenated counterpart, Dfrac) is an evolutionary indicator both in the low- and the
high-mass star formation process. However, the role of surface chemistry in these studies has not been quantified from an observational point of view. In order to compare how the deuterated fractions of species formed only in the gas and partially or uniquely on grain surfaces evolve with time, we observed rotational transitions of CH3OH, 13CH3OH, CH2DOH, CH3OD at 3 and 1.3~mm, and of NH2D at 3~mm with the IRAM-30m telescope, and the inversion transitions (1,1) and (2,2) of NH3 with the GBT, towards most of the cores already observed by Fontani et al.~(2011, 2014) in N2H+, N2D+, HNC, DNC. NH2D is detected in all but two cores, regardless of the evolutionary stage. Dfrac(NH3) is on average above 0.1, and does not change significantly from the earliest to the most evolved phases, although the highest average value is found in the protostellar phase (~0.3). Few lines of CH2DOH and CH3OD are clearly detected, and only towards protostellar cores or externally heated starless cores. This work clearly confirms an expected different evolutionary trend of the species formed exclusively in the gas (N2D+ and N2H+) and those formed partially (NH2D and NH3) or totally (CH2DOH and CH3OH) on grain mantles. The study also reinforces the idea that Dfrac(N2H+) is the best tracer of massive starless cores, while high values of Dfrac(CH3OH) seem rather good tracers of the early protostellar phases, at which the evaporation/sputtering of the grain mantles is most efficient.
Molecular outflows powered by young protostars strongly affect the kinematics and chemistry of the natal molecular cloud through strong shocks resulting in substantial modifications of the abundance of several species. As part of the Chemical Hersche
l Surveys of Star forming regions guaranteed time key program, we aim at investigating the physical and chemical conditions of H20 in the brightest shock region B1 of the L1157 molecular outflow. We observed several ortho- and para-H2O transitions using HIFI and PACS instruments on board Herschel, providing a detailed picture of the kinematics and spatial distribution of the gas. We performed a LVG analysis to derive the physical conditions of H2O shocked material, and ultimately obtain its abundance. We detected 13 H2O lines probing a wide range of excitation conditions. PACS maps reveal that H2O traces weak and extended emission associated with the outflow identified also with HIFI in the o-H2O line at 556.9 GHz, and a compact (~10) bright, higher-excitation region. The LVG analysis of H2O lines in the bow-shock show the presence of two gas components with different excitation conditions: a warm (Tkin~200-300 K) and dense (n(H2)~(1-3)x10^6 cm-3) component with an assumed extent of 10 and a compact (~2-5) and hot, tenuous (Tkin~900-1400 K, n(H2)~10^3-10^4 cm-3) gas component, which is needed to account for the line fluxes of high Eu transitions. The fractional abundance of the warm and hot H2O gas components is estimated to be (0.7-2)x10^{-6} and (1-3)x10^{-4}, respectively. Finally, we identified an additional component in absorption in the HIFI spectra of H2O lines connecting with the ground state level, probably arising from the photodesorption of icy mantles of a water-enriched layer at the edges of the cloud.
The deuterium fractionation, Dfrac, has been proposed as an evolutionary indicator in pre-protostellar and protostellar cores of low-mass star-forming regions. We investigate Dfrac, with high angular resolution, in the cluster environment surrounding
the UCHII region IRAS 20293+3952. We performed high angular resolution observations with the IRAM Plateau de Bure Interferometer (PdBI) of the ortho-NH2D 1_{11}-1_{01} line at 85.926 GHz and compared them with previously reported VLA NH3 data. We detected strong NH2D emission toward the pre-protostellar cores identified in NH3 and dust emission, all located in the vicinity of the UCHII region IRAS 20293+3952. We found high values of Dfrac~0.1-0.8 in all the pre-protostellar cores and low values, Dfrac<0.1, associated with young stellar objects. The high values of Dfrac in pre-protostellar cores could be indicative of evolution, although outflow interactions and UV radiation could also play a role.
We aim at studying with high angular resolution a dense core associated with a low-luminosity IRAS source, IRAS 00213+6530, in order to investigate whether low mass star formation is really taking place in isolation. We performed observations at 1.2m
m with the IRAM 30m telescope, VLA observations at 6cm, 3.6cm, 1.3cm, 7mm, and H2O maser and NH3 lines, and observations with the NASA 70m antenna in CCS and H2O maser. The cm and mm continuum emission, together with the near infrared data from the 2MASS allowed us to identify 3 YSOs, IRS1, VLA8A, and VLA8B, with different radio and infrared properties, and which seem to be in different evolutionary stages. The NH3 emission consists of three clouds. Two of these, MM1 and MM2, are associated with dust emission, while the southern cloud is only detected in NH3. The YSOs are embedded in MM1, where we found evidence of line broadening and temperature enhancements. On the other hand, the southern cloud and MM2 appear to be quiescent and starless. We modeled the radial intensity profile at 1.2mm of MM1. The model fits reasonably well the data, but it underestimates the intensity at small projected distances from the 1.2mm peak, probably due to the presence of multiple YSOs embedded in the envelope. There is a differentiation in the relative NH3 abundance with low values, ~2x10^-8, toward MM1, and high values, up to 10^-6, toward the southern cloud and MM2, suggesting that these clouds could be in a young evolutionary stage. IRAS 00213+6530 is harboring a multiple system of low-mass protostars, indicating that star formation in this cloud is taking place in groups, rather than in isolation. The low-mass YSOs found in IRAS 00213+6530 are in different evolutionary stages suggesting that star formation is taking place in different episodes.
