TetraPhenyl Butadiene is the wavelength shifter most widely used in combination with liquid Argon. The latter emits scintillation photons with a wavelength of 127 nm that need to be downshifted to be detected by photomultipliers with glass or quartz
windows. TetraPhenyl Butadiene has been demonstrated to have an extremely high conversion efficiency, possibly higher than 100 % for 127 nm photons, while there is no precise information about the time dependence of its emission. It is usually assumed to be exponentially decaying with a characteristic time of the order of one ns, as an extrapolation from measurements with exciting radiation in the near UV. This work shows that TetraPhenyl Butadiene, when excited by 127 nm photons, reemits photons not only with a very short decay time, but also with slower ones due to triplet states de-excitations. This fact can strongly contribute to clarify the anomalies in liquid Argon scintillation light reported in literature since seventies, namely the inconsistency in the measured values of the long decay time constant and the appearance of an intermediate component. Similar effects should be also expected when the TPB is used in combination with Helium and Neon, that emit scintillation photons with wavelengths shorter than 127 nm.
A simple model for the estimation of the light yield of a scintillation detector is developed under general assumptions and relying exclusively on the knowledge of its optical properties. The model allows to easily incorporate effects related to Rayl
eigh scattering and absorption of the photons.The predictions of the model are benchmarked with the outcomes of Monte Carlo simulations of specific scintillation detectors. An accuracy at the level of few percent is achieved. The case of a real liquid argon based detector is explicitly treated and the predicted light yield is compared with the measured value.
