The rotationally resolved spectrum of the B$^2Pi-$X$^2Pi$ electronic origin band transition of $^{13}$C$_6$H is presented. The spectrum is recorded using cavity ring-down spectroscopy in combination with supersonic plasma jets by discharging a $^{13}
$C$_2$H$_2$/He/Ar gas mixture. A detailed analysis of more than a hundred fully-resolved transitions allows for an accurate determination of the spectroscopic parameters for both the ground and electronically excited state of $^{13}$C$_6$H.
Spectra of molecular hydrogen (H$_2$) are employed to search for a possible proton-to-electron mass ratio ($mu$) dependence on gravity. The Lyman transitions of H$_2$, observed with the Hubble Space Telescope towards white dwarf stars that underwent
a gravitational collapse, are compared to accurate laboratory spectra taking into account the high temperature conditions ($T sim 13,000$ K) of their photospheres. We derive sensitivity coefficients $K_i$ which define how the individual H$_2$ transitions shift due to $mu$-dependence. The spectrum of white dwarf star GD133 yields a $Deltamu/mu$ constraint of $(-2.7pm4.7_{rm stat}pm 0.2_{rm sys})times10^{-5}$ for a local environment of a gravitational potential $phisim10^4 phi_textrm{Earth}$, while that of G29$-$38 yields $Deltamu/mu=(-5.8pm3.8_{rm stat}pm 0.3_{rm sys})times10^{-5}$ for a potential of $2 times 10^4$ $phi_textrm{Earth}$.
An extensive survey of the D2 absorption spectrum has been performed with the high-resolution VUV Fourier-transform spectrometer of the DESIRS beamline at the SOLEIL synchrotron. The frequency range of 90 000-119 000 cm-1 covers the full depth of the
potential wells of the B 1{Sigma}+u, B 1{Sigma}+u, and C 1{Pi}u electronic states up to the D(1s) + D(2ell) dissociation limit. Improved level energies of rovibrational levels have been determined up to respectively v = 51, v = 13, and v = 20. Highest resolution is achieved by probing absorption in a molecular gas jet with slit geometry, as well as in a liquid helium cooled static gas cell, resulting in line widths of ~0.35 cm-1. Extended calibration methods are employed to extract line positions of D2 lines at absolute accuracies of 0.03 cm-1. The D1{Pi}u and B 1{Sigma}+u electronic states correlate with the D(1s) + D(3ell) dissociation limit, but support a few vibrational levels below the second dissociation limit, respectively v = 0-3 and v = 0-1, and are also included in the presented study. The complete set of resulting level energies is the most comprehensive and accurate data set for D2. The observations are compared with previous studies, both experimental and theoretical.
UV frequency metrology has been performed on the a3Pi - X1Sigma+ (0,0) band of various isotopologues of CO using a frequency-quadrupled injection-seeded narrow-band pulsed Titanium:Sapphire laser referenced to a frequency comb laser. The band origin
is determined with an accuracy of 5 MHz (delta u / u = 3 * 10^-9), while the energy differences between rotational levels in the a3Pi state are determined with an accuracy of 500 kHz. From these measurements, in combination with previously published radiofrequency and microwave data, a new set of molecular constants is obtained that describes the level structure of the a3Pi state of 12C16O and 13C16O with improved accuracy. Transitions in the different isotopologues are well reproduced by scaling the molecular constants of 12C16O via the common mass-scaling rules. Only the value of the band origin could not be scaled, indicative of a breakdown of the Born-Oppenheimer approximation. Our analysis confirms the extreme sensitivity of two-photon microwave transitions between nearly-degenerate rotational levels of different Omega-manifolds for probing a possible variation of the proton-to-electron mass ratio, mu=m_p/m_e, on a laboratory time scale.
