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We report the fabrication and characterization of a Ti$^{4+}$:Tm$^{3+}$:LiNbO$_3$ optical waveguide in view of photon-echo quantum memory applications. In particular, we investigated room- and cryogenic-temperature properties via absorption, spectral hole burning, photon echo, and Stark spectroscopy. We found radiative lifetimes of 82 $mu$s and 2.4 ms for the $^3$H$_4$ and $^3$F$_4$ levels, respectively, and a 44% branching ratio from the $^3$H$_{4}$ to the $^3$F$_4$ level. We also measured an optical coherence time of 1.6 $mu$s for the $^3$H$_6leftrightarrow{}^3$H$_4$, 795 nm wavelength transition, and investigated the limitation of spectral diffusion to spectral hole burning. Upon application of magnetic fields of a few hundred Gauss, we observed persistent spectral holes with lifetimes up to seconds. Furthermore, we measured a linear Stark shift of 25 kHz$cdot$cm/V. Our results are promising for integrated, electro-optical, waveguide quantum memory for photons.
Quantum memory is a key element for quantum repeaters and linear optical quantum computers. In addition to memory, repeaters and computers also require manipulating quantum states by means of unitary transformations, which is generally accomplished u sing interferometric optical setups. We experimentally investigate photon-echo type atom-light interaction for the possibility to combine storage with controlled transformation of quantum states. As an example, we demonstrate unambiguous state discrimination of qubits and qutrits in an Ti:Er:LiNbO$_3$ waveguide cooled to 3K using states encoded into large ensembles of identically prepared photons in superposition of different temporal modes. The high robustness and flexibility of our approach makes it promising for quantum communication and computation as well as precision measurements.
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