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Pressure is the cleanest way to tune heavy fermion systems to a quantum phase transition in order to study the rich physics and competing phases, and the comparison between ytterbium and cerium systems is particularly fruitful. We briefly review the mechanisms in play and show some examples of expected and unexpected behaviour. We emphasize the importance of the valence changes under pressure and show how modern synchrotron techniques can accurately determine this, including at low temperature.
The ab-plane resistivity of Ba(Fe1-xRux)2As2 (x = 0.00, 0.09, 0.16, 0.21, and 0.28) was studied under nearly hydrostatic pressures, up to 7.4 GPa, in order to explore the T-P phase diagram and to compare the combined effects of iso-electronic Ru subs titution and pressure. The parent compound BaFe2As2 exhibits a structural/magnetic phase transition near 134 K. At ambient pressure, progressively increasing Ru concentration suppresses this phase transition to lower temperatures at the approximate rate of ~5 K/% Ru and is correlated with the emergence of superconductivity. By applying pressure to this system, a similar behavior is seen for each concentration: the structural/magnetic phase transition is further suppressed and superconductivity induced and ultimately, for larger x Ru and P, suppressed. A detailed comparison of the T-P phase diagrams for all Ru concentrations shows that 3 GPa of pressure is roughly equivalent to 10% Ru substitution. Furthermore, due to the sensitivity of Ba(Fe1-xRux)2As2 to pressure conditions, the melting of the liquid media, 4 : 6 light mineral oil : n-pentane and 1 : 1 iso-pentane : n-pentane, used in this study could be readily seen in the resistivity measurements. This feature was used to determine the freezing curves for these media and infer their room temperature, hydrostatic limits: 3.5 and 6.5 GPa, respectively.
We present temperature dependent resistivity and ac-calorimetry measurements of CeVSb3 under pressure up to 8 GPa in a Bridgman anvil cell modified to use a liquid medium and in a diamond anvil cell using argon as a pressure medium, respectively. We observe an initial increase of the ferromagnetic transition temperature Tc with pressures up to 4.5 GPa, followed by decrease of Tc on further increase of pressure and finally its disappearance, in agreement with the Doniach model. We infer a ferromagnetic quantum critical point around 7 GPa under hydrostatic pressure conditions from the extrapolation to 0 K of Tc and the maximum of the A coefficient from low temperature fits of the resistivity rho (T)=rho_{0}+AT^{n}. No superconductivity under pressure was observed down to 0.35 K for this compound. In addition, differences in the Tc(P) behavior when a slight uniaxial component is present are noticed and discussed and correlated to choice of pressure medium.
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