We present Submillimeter Array (SMA) observations of several deuterated species in the disk around the classical T Tauri star TW Hydrae at arcsecond scales, including detections of the DCN J=3-2 and DCO+ J=3-2 lines, and upper limits to the HDO 3(1,2
)-2(2,1), ortho-H2D+ 1(1,0)-1(1,1) and para-D2H+ 1(1,0)-1(0,1) transitions. We also present observations of the HCN J=3-2, HCO+ J=3-2 and H13CO+ J=4-3 lines for comparison with their deuterated isotopologues. We constrain the radial and vertical distributions of various species in the disk by fitting the data using a model where the molecular emission from an irradiated accretion disk is sampled with a 2D Monte Carlo radiative transfer code. We find that the distribution of DCO+ differs markedly from that of HCO+. The D/H ratios inferred change by at least one order of magnitude (0.01 to 0.1) for radii <30 AU to >70 AU and there is a rapid falloff of the abundance of DCO+ at radii larger than 90 AU. Using a simple analytical chemical model, we constrain the degree of ionization, x(e-)=n(e-)/n(H2), to be ~10^-7 in the disk layer(s) where these molecules are present. Provided the distribution of DCN follows that of HCN, the ratio of DCN to HCN is determined to be 1.7pm0.5 times 10^-2; however, this ratio is very sensitive to the poorly constrained vertical distribution of HCN. The resolved radial distribution of DCO+ indicates that {it in situ} deuterium fractionation remains active within the TW Hydrae disk and must be considered in the molecular evolution of circumstellar accretion disks.
