We combine Herschel observations of a total of 12 sources to construct the most uniform survey of HF and H2O in our Galactic disk. Both molecules are detected in absorption along all sight lines. The high spectral resolution of the Heterodyne Instrum
ent for the Far-Infrared (HIFI) allows us to compare the HF and H2O distributions in 47 diffuse cloud components sampling the disk. We find that the HF and H2O velocity distributions follow each other almost perfectly and establish that HF and H2O probe the same gas-phase volume. Our observations corroborate theoretical predictions that HF is a sensitive tracer of H2 in diffuse clouds, down to molecular fractions of only a few percent. Using HF to trace H2 in our sample, we find that the N(H2O)-to-N(HF) ratio shows a narrow distribution with a median value of 1.51. Our results further suggest that H2O might be used as a tracer of H2 -within a factor 2.5- in the diffuse interstellar medium. We show that the measured factor of ~2.5 variation around the median is driven by true local variations in the H2O abundance relative to H2 throughout the disk. The latter variability allows us to test our theoretical understanding of the chemistry of oxygen-bearing molecules in the diffuse gas. We show that both gas-phase and grain-surface chemistry are required to reproduce our H2O observations. This survey thus confirms that grain surface reactions can play a significant role in the chemistry occurring in the diffuse interstellar medium n_H < 1000 cm^-3.
We present an analysis of Spitzer-IRS spectroscopic maps of the L1157 protostellar outflow in the H2 pure-rotational lines from S(0) to S(7). The aim of this work is to derive the physical conditions pertaining to the warm molecular gas and study the
ir variations within the flow. The mid-IR H2 emission follows the morphology of the precessing flow, with peaks correlated with individual CO clumps and H2 2.12{mu}m ro-vibrational emission. More diffuse emission delineating the CO cavities is detected only in the low-laying transitions, with J(lower) less or equal to 2. The H2 line images have been used to construct 2D maps of N(H2), H2 ortho-to-para ratio and temperature spectral index beta, in the assumption of a gas temperature stratification where the H2 column density varies as T^(beta). Variations of these parameters are observed along the flow. In particular, the ortho-to-para ratio ranges from 0.6 to 2.8, highlighting the presence of regions subject to recent shocks where the ortho-to-para ratio has not had time yet to reach the equilibrium value. Near-IR spectroscopic data on ro-vibrational H2 emission have been combined with the mid-IR data and used to derive additional shock parameters in the brightest blue- and red-shifted emission knots. A high abundance of atomic hydrogen (H/H2 about 0.1-0.3) is implied by the observed H2 column densities, assuming n(H2) values as derived by independent SiO observations. The presence of a high fraction of atomic hydrogen, indicates that a partially-dissociative shock component should be considered for the H2 excitation in these localized regions. However, planar shock models, either of C- or J-type, are not able to consistently reproduce all the physical parameters derived from our analysis of the H2 emission. Globally, H2 emission contributes to about 50% of the total shock radiated energy in the L1157 outflow.
