We develop a method to predict the existence of edge states in graphene ribbons for a large class of boundaries. This approach is based on the bulk-edge correspondence between the quantized value of the Zak phase Z(k), which is a Berry phase across a
n appropriately chosen one-dimensional Brillouin zone, and the existence of a localized state of momentum k at the boundary of the ribbon. This bulk-edge correspondence is rigorously demonstrated for a one dimensional toy model as well as for graphene ribbons with zigzag edges. The range of k for which edge states exist in a graphene ribbon is then calculated for arbitrary orientations of the edges. Finally, we show that the introduction of an anisotropy leads to a topological transition in terms of the Zak phase, which modifies the localization properties at the edges. Our approach gives a new geometrical understanding of edge states, it confirms and generalizes the results of several previous works.
We consider an impurity with a spin degree of freedom coupled to a finite reservoir of non-interacting electrons, a system which may be realized by either a true impurity in a metallic nano-particle or a small quantum dot coupled to a large one. We s
how how the physics of such a spin impurity is revealed in the many-body spectrum of the entire finite-size system; in particular, the evolution of the spectrum with the strength of the impurity-reservoir coupling reflects the fundamental many-body correlations present. Explicit calculation in the strong and weak coupling limits shows that the spectrum and its evolution are sensitive to the nature of the impurity and the parity of electrons in the reservoir. The effect of the finite size spectrum on two experimental observables is considered. First, we propose an experimental setup in which the spectrum may be conveniently measured using tunneling spectroscopy. A rate equation calculation of the differential conductance suggests how the many-body spectral features may be observed. Second, the finite-temperature magnetic susceptibility is presented, both the impurity susceptibility and the local susceptibility. Extensive quantum Monte-Carlo calculations show that the local susceptibility deviates from its bulk scaling form. Nevertheless, for special assumptions about the reservoir -- the clean Kondo box model -- we demonstrate that finite-size scaling is recovered. Explicit numerical evaluations of these scaling functions are given, both for even and odd parity and for the canonical and grand-canonical ensembles.
We study Fermi edge singularities in photo-absorption spectra of generic mesoscopic systems such as quantum dots or nanoparticles. We predict deviations from macroscopic-metallic behavior and propose experimental setups for the observation of these e
ffects. The theory is based on the model of a localized, or rank one, perturbation caused by the (core) hole left behind after the photo-excitation of an electron into the conduction band. The photo-absorption spectra result from the competition between two many-body responses, Andersons orthogonality catastrophe and the Mahan-Nozieres-DeDominicis contribution. Both mechanisms depend on the system size through the number of particles and, more importantly, fluctuations produced by the coherence characteristic of mesoscopic samples. The latter lead to a modification of the dipole matrix element and trigger one of our key results: a rounded K-edge typically found in metals will turn into a (slightly) peaked edge on average in the mesoscopic regime. We consider in detail the effect of the bound state produced by the core hole.
