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81 - A. Camposeo 2015
Nanofibers functionalized by metal nanostructures and particles are exploited as effective flexible substrates for SERS analysis. Their complex three-dimensional structure may provide Raman signals enhanced by orders of magnitude compared to untextur ed surfaces. Understanding the origin of such improved performances is therefore very important for pushing nanofiber-based analytical technologies to their upper limit. Here we report on polymer nanofiber mats which can be exploited as substrates for enhancing the Raman spectra of adsorbed probe molecules. The increased surface area and the scattering of light in the nanofibrous system are individually analyzed as mechanisms to enhance Raman scattering. The deposition of gold nanorods on the fibers further amplifies Raman signals due to SERS. This study suggests that Raman signals can be finely tuned in intensity and effectively enhanced in nanofiber mats and arrays by properly tailoring the architecture, composition, and light-scattering properties of the complex networks of filaments.
In the last 30 years, the existence of small and cool magnetic loops (height < 8 Mm, T < 10^5 K) has been proposed and debated to explain the increase of the DEM (differential emission measure) towards the chromosphere. We present hydrodynamic simula tions of low-lying cool loops to study their conditions of existence and stability, and their contribution to the transition region EUV output. We find that stable, quasi-static cool loops (with velocities < 1 km/s) can be obtained under different and more realistic assumptions on the radiative losses function with respect to previous works. A mixture of the DEMs of these cool loops plus intermediate loops with temperatures between 10^5 and 10^6 K can reproduce the observed emission of the lower transition region at the critical turn-up temperature point (T ~ 2x10^5 K) and below T = 10^5 K.
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