(abbreviated) We aim to study the inner wind of the well-known AGB star CW Leo. Different diagnostics probing different geometrical scales have pointed toward a non-homogeneous mass-loss process: dust clumps are observed at milli-arcsec scale, a bipo
lar structure is seen at arcsecond-scale and multi-concentric shells are detected beyond 1. We present the first ALMA Cycle 0 band 9 data around 650 GHz. The full-resolution data have a spatial resolution of 0.42x0.24, allowing us to study the morpho-kinematical structure within ~6. Results: We have detected 25 molecular lines. The emission of all but one line is spatially resolved. The dust and molecular lines are centered around the continuum peak position. The dust emission has an asymmetric distribution with a central peak flux density of ~2 Jy. The molecular emission lines trace different regions in the wind acceleration region and suggest that the wind velocity increases rapidly from about 5 R* almost reaching the terminal velocity at ~11 R*. The channel maps for the brighter lines show a complex structure; specifically for the 13CO J=6-5 line different arcs are detected within the first few arcseconds. The curved structure present in the PV map of the 13CO J=6-5 line can be explained by a spiral structure in the inner wind, probably induced by a binary companion. From modeling the ALMA data, we deduce that the potential orbital axis for the binary system lies at a position angle of ~10-20 deg to the North-East and that the spiral structure is seen almost edge-on. We infer an orbital period of 55 yr and a binary separation of 25 au (or ~8.2 R*). We tentatively estimate that the companion is an unevolved low-mass main-sequence star. The ALMA data hence provide us for the first time with the crucial kinematical link between the dust clumps seen at milli-arcsecond scale and the almost concentric arcs seen at arcsecond scale.
We model the production of OH+, H2O+, and H3O+ in interstellar clouds, using a steady state photodissociation region code that treats the freeze-out of gas species, grain surface chemistry, and desorption of ices from grains. The code includes PAHs,
which have important effects on the chemistry. All three ions generally have two peaks in abundance as a function of depth into the cloud, one at A_V<~1 and one at A_V~3-8, the exact values depending on the ratio of incident ultraviolet flux to gas density. For relatively low values of the incident far ultraviolet flux on the cloud ({chi}<~ 1000; {chi}= 1= local interstellar value), the columns of OH+ and H2O+ scale roughly as the cosmic ray primary ionization rate {zeta}(crp) divided by the hydrogen nucleus density n. The H3O+ column is dominated by the second peak, and we show that if PAHs are present, N(H3O+) ~ 4x10^{13} cm^{-2} independent of {zeta}(crp) or n. If there are no PAHs or very small grains at the second peak, N(H3O+) can attain such columns only if low ionization potential metals are heavily depleted. We also model diffuse and translucent clouds in the interstellar medium, and show how observations of N(OH+)/N(H) and N(OH+)/N(H2O+) can be used to estimate {zeta}(crp)/n, {chi}/n and A_V in them. We compare our models to Herschel observations of these two ions, and estimate {zeta}(crp) ~ 4-6 x 10^-16 (n/100 cm^-3) s^-1 and chi/n = 0.03 cm^3 for diffuse foreground clouds towards W49N.
