In this paper, the notion of proper proximality (introduced in [BIP18]) is studied for various families of groups that act on trees. We show that if a group acts non-elementarily by isometries on a tree such that for any two edges, the intersection o
f their edge stabilizers is finite, then G is properly proximal. We then provide a complete classification result for proper proximality among graph products of non-trivial groups, generalizing recent work of Duchesne, Tucker-Drob and Wesolek classifying inner amenability for graph products. As a consequence of the above result we obtain the absence of Cartan subalgebras and Cartan-rigidity in properly proximal graph products of weakly amenable groups with Cowling-Haagerup constant 1.
