OH 231.8+4.2, a bipolar outflow around a Mira-type variable star, displays a unique molecular richness amongst circumstellar envelopes (CSEs) around O-rich AGB and post-AGB stars. We report line observations of the HCO+ and H13CO+ molecular ions and
the first detection of SO+, N2H+, and (tentatively) H3O+ in this source. SO+ and H3O+ have not been detected before in CSEs around evolved stars. These data have been obtained as part of a full mm-wave and far-IR spectral line survey carried out with the IRAM 30 m radio telescope and with Herschel/HIFI. Except for H3O+, all the molecular ions detected in this work display emission lines with broad profiles (FWHM 50-90 km/s), which indicates that these ions are abundant in the fast bipolar outflow of OH 231.8. The narrow profile (FWHM 14 km/s) and high critical densities (>1e6cm-3 ) of the H3O+ transitions observed are consistent with this ion arising from denser, inner (and presumably warmer) layers of the fossil remnant of the slow AGB CSE at the core of the nebula. From rotational diagram analysis, we deduce excitation temperatures of Tex 10-20 K for all ions except for H3O+, which is most consistent with Tex 100 K. Although uncertain, the higher excitation temperature suspected for H3O+ is similar to that recently found for H2O and a few other molecules, which selectively trace a previously unidentified, warm nebular component.The column densities of the molecular ions reported here are in the range Ntot [1-8]x1e13 cm-2, leading to beam-averaged fractional abundances relative to H2 of X(HCO+) 1e-8, X(H13CO+) 2e-9, X(SO+) 4e-9, X(N2H+) 2e-9, and X(H3O+) 7e-9 cm-2. We have performed chemical kinetics models to investigate the formation of these ions in OH 231.8 as the result of standard gas phase reactions initiated by cosmic-ray and UV-photon ionization. (abridged).
We present echelle long-slit optical spectra of a sample of objects evolving off the AGB, most of them in the pre-planetary nebula (pPN) phase, obtained with the ESI and MIKE spectrographs at Keck-II and Magellan-I, respectively. The total wavelength
range covered with ESI (MIKE) is ~3900 to 10900 A (~3600 to 7200A). In this paper, we focus our analysis mainly on the Halpha profiles. Prominent Halpha emission is detected in half of the objects, most of which show broad Halpha wings (up to ~4000 km/s). In the majority of the Halpha-emission sources, fast, post-AGB winds are revealed by P-Cygni profiles. In ~37% of the objects Halpha is observed in absorption. In almost all cases, the absorption profile is partially filled with emission, leading to complex, structured profiles that are interpreted as an indication of incipient post-AGB mass-loss. All sources in which Halpha is seen mainly in absorption have F-G type central stars, whereas sources with intense Halpha emission span a larger range of spectral types from O to G. Shocks may be an important excitation agent of the close stellar surroundings for objects with late type central stars. Sources with pure emission or P Cygni Halpha profiles have larger J-K color excess than objects with Halpha mainly in absorption, which suggests the presence of warm dust near the star in the former. The two classes of profile sources also segregate in the IRAS color-color diagram in a way that intense Halpha-emitters have dust grains with a larger range of temperatures. (abridged)
