We present an observational reconstruction of the radial water vapor content near the surface of the TW Hya transitional protoplanetary disk, and report the first localization of the snow line during this phase of disk evolution. The observations are
comprised of Spitzer-IRS, Herschel-PACS, and Herschel-HIFI archival spectra. The abundance structure is retrieved by fitting a two-dimensional disk model to the available star+disk photometry and all observed H2O lines, using a simple step-function parameterization of the water vapor content near the disk surface. We find that water vapor is abundant (~10^{-4} per H2) in a narrow ring, located at the disk transition radius some 4AU from the central star, but drops rapidly by several orders of magnitude beyond 4.2 AU over a scale length of no more than 0.5AU. The inner disk (0.5-4AU) is also dry, with an upper limit on the vertically averaged water abundance of 10^{-6} per H2. The water vapor peak occurs at a radius significantly more distant than that expected for a passive continuous disk around a 0.6 Msun star, representing a volatile distribution in the TW Hya disk that bears strong similarities to that of the solar system. This is observational evidence for a snow line that moves outward with time in passive disks, with a dry inner disk that results either from gas giant formation or gas dissipation and a significant ice reservoir at large radii. The amount of water present near the snow line is sufficient to potentially catalyze the (further) formation of planetesimals and planets at distances beyond a few AU.
We present an analysis of Spitzer-IRS observations of H2O, OH, HCN, C2H2, and CO2 emission, and Keck-NIRSPEC observations of CO emission, from a diverse sample of T Tauri and Herbig Ae/Be circumstellar disks. We find that detections and strengths of
most mid-IR molecular emission features are correlated with each other, suggesting a common origin and similar excitation conditions. We note that the line detection efficiency is anti-correlated with the 13/30 um SED spectral slope, which is a measure of the degree of grain settling in the disk atmosphere. We also note a correlation between detection efficiency and H-alpha equivalent width, and tentatively with accretion rate, suggesting that accretional heating contributes to line excitation. If detected, H2O line fluxes are correlated with the mid-IR continuum flux, and other co-varying system parameters, such as L_star. However, significant sample variation, especially in molecular line ratios, remains. LTE models of the H2O emission show that line strength is primarily related to the best-fit emitting area, and this accounts for most source-to-source variation in H2O emitted flux. Best-fit temperatures and column densities cover only a small range of parameter space, near 10^{18} cm-2 and 450 K for all sources, suggesting a high abundance of H2O in many planet-forming regions. Other molecules have a range of excitation temperatures from ~500-1500 K, also consistent with an origin in planet-forming regions. We find molecular ratios relative to water of ~10^{-3} for all molecules, with the exception of CO, for which n(CO)/n(H2O)~1. However, LTE fitting caveats and differences in the way thermo-chemical modeling results are reported make comparisons with such models difficult, and highlight the need for additional observations coupled with the use of line-generating radiative transfer codes.
We present detections of numerous 10-20 micron H2O emission lines from two protoplanetary disks around the T Tauri stars AS 205A and DR Tau, obtained using the InfraRed Spectrograph on the Spitzer Space Telescope. Follow-up 3-5 micron Keck-NIRSPEC da
ta confirm the presence of abundant water and spectrally resolve the lines. We also detect the P4.5 (2.934 micron) and P9.5 (3.179 micron) doublets of OH and 12CO/13CO v=1-0 emission in both sources. Line shapes and LTE models suggest that the emission from all three molecules originates between ~0.5 and 5 AU, and so will provide a new window for understanding the chemical environment during terrestrial planet formation. LTE models also imply significant columns of H2O and OH in the inner disk atmospheres, suggesting physical transport of volatile ices either vertically or radially; while the significant radial extent of the emission stresses the importance of a more complete understanding of non-thermal excitation processes.
