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Chandra high-resolution spectra toward eight low-mass Galactic binaries have been analyzed with a photoionization model that is capable of determining the physical state of the interstellar medium. Particular attention is given to the accuracy of the atomic data. Hydrogen column densities are derived with a broadband fit that takes into account pileup effects, and in general are in good agreement with previous results. The dominant features in the oxygen-edge region are O I and O II K$alpha$ absorption lines whose simultaneous fits lead to average values of the ionization parameter of $logxi=-2.90$ and oxygen abundance of $A_{rm O}=0.70$. The latter is relative to the standard by Grevesse & Sauval (1998), but a rescaling with the revision by Asplund et al. (2009) would lead to an average abundance value fairly close to solar. The low average oxygen column density ($N_{rm O}=9.2 times 10^{17}$ cm$^{-2}$) suggests a correlation with the low ionization parameters, the latter also being in evidence in the column density ratios OII/OI and OIII/OI that are estimated to be less than 0.1. We do not find conclusive evidence for absorption by any other compound but atomic oxygen.
The classic optical nebular diagnostics [N II], [O II], [O III], [S II], [S III], and [Ar III] are employed to search for evidence of non-Maxwellian electron distributions, namely $kappa$ distributions, in a sample of well-observed Galactic H II regi ons. By computing new effective collision strengths for all these systems and A-values when necessary (e.g. S II), and by comparing with previous collisional and radiative datasets, we have been able to obtain realistic estimates of the electron-temperature dispersion caused by the atomic data, which in most cases are not larger than $sim 10$%. If the uncertainties due to both observation and atomic data are then taken into account, it is plausible to determine for some nebulae a representative average temperature while in others there are at least two plasma excitation regions. For the latter, it is found that the diagnostic temperature differences in the high-excitation region, e.g. $T_e$(O III), $T_e$(S III), and $T_e$(Ar III), cannot be conciliated by invoking $kappa$ distributions. For the low excitation region, it is possible in some, but not all, cases to arrive at a common, lower temperature for [N II], [O II], and [S II] with $kappaapprox 10$, which would then lead to significant abundance enhancements for these ions. An analytic formula is proposed to generate accurate $kappa$-averaged excitation rate coefficients (better than 10% for $kappa geq 5$) from temperature tabulations of the Maxwell-Boltzmann effective collision strengths.
Radiative and Auger decay data have been calculated for modelling the K lines in ions of the nickel isonuclear sequence, from Ni$^+$ up to Ni$^{27+}$. Level energies, transition wavelengths, radiative transition probabilities, and radiative and Auger widths have been determined using Cowans Hartree--Fock with Relativistic corrections (HFR) method. Auger widths for the third-row ions (Ni$^+$--Ni$^{10+}$) have been computed using single-configuration average (SCA) compact formulae. Results are compared with data sets computed with the AUTOSTRUCTURE and MCDF atomic structure codes and with available experimental and theoretical values, mainly in highly ionized ions and in the solid state.
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