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The thermodynamic properties of the ferromagnetic perovskite YTiO$_3$ are investigated by thermal expansion, magnetostriction, specific heat, and magnetization measurements. The low-temperature spin-wave contribution to the specific heat, as well as an Arrott plot of the magnetization in the vicinity of the Curie temperature $T_Csimeq27$ K, are consistent with a three-dimensional Heisenberg model of ferromagnetism. However, a magnetic contribution to the thermal expansion persists well above $T_C$, which contrasts with typical three-dimensional Heisenberg ferromagnets, as shown by a comparison with the corresponding model system EuS. The pressure dependences of $T_C$ and of the spontaneous moment $M_s$ are extracted using thermodynamic relationships. They indicate that ferromagnetism is strengthened by uniaxial pressures $mathbf{p}parallel mathbf{a}$ and is weakened by uniaxial pressures $mathbf{p}parallel mathbf{b},mathbf{c}$ and hydrostatic pressure. Our results show that the distortion along the $a$- and $b$-axes is further increased by the magnetic transition, confirming that ferromagnetism is favored by a large GdFeO$_3$-type distortion. The c-axis results however do not fit into this simple picture, which may be explained by an additional magnetoelastic effect, possibly related to a Jahn-Teller distortion.
The weak itinerant ferromagnet UIr is studied by magnetization and magnetostriction measurements. Critical behavior, which surprisingly extends up to several Tesla, is observed at the Curie temperature $T_Csimeq45$ K and is analyzed using Arrott and Maxwell relations. Critical exponents are found that do not match with any of the well-known universality classes. The low-temperature magnetization $M_ssimeq0.5$ $mu_B cong const.$ below 3 T rises towards higher fields and converges asymptotically around 50 T with the magnetization at $T_C$. From the magnetostriction and magnetization data, we extract the uniaxial pressure dependences of $T_C$, using a new method presented here, and of $M_s$. These results should serve as a basis for understanding spin fluctuations in anisotropic itinerant ferromagnets.
400 - W. Knafo , C. Meingast , A. Inaba 2008
A study by specific heat of a polycrystalline sample of the low-dimensional magnetic system Y$_2$BaCuO$_5$ is presented. Magnetic fields up to 14 T are applied and permit to extract the ($T$,$H$) phase diagram. Below $mu_0H^*simeq2$ T, the Neel tempe rature, associated with a three-dimensional antiferromagnetic long-range ordering, is constant and equals $T_N=15.6$ K. Above $H^*$, $T_N$ increases linearly with $H$ and a field-induced increase of the entropy at $T_N$ is related to the presence of an isosbestic point at $T_Xsimeq20$ K, where all the specific heat curves cross. A comparison is made between Y$_2$BaCuO$_5$ and the quasi-two-dimensional magnetic systems BaNi$_{2}$V$_{2}$O$_{8}$, Sr$_2$CuO$_2$Cl$_2$, and Pr$_2$CuO$_4$, for which very similar phase diagrams have been reported. An effective field-induced magnetic anisotropy is proposed to explain these phase diagrams.
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