Spin/magnetisation relaxation and coherence times, respectively T_1 and T_2, initially defined in the context of nuclear magnetic resonance (NMR), are general concepts applicable to a wide range of systems, including quantum bits [1-4]. At first glan
ce, these ideas might seem to be irrelevant to conventional Bardeen-Cooper-Schrieffer (BCS) superconductors, as the BCS superconducting ground state is a condensate of Cooper pairs of electrons with opposite spins (in a singlet state) [5]. It has recently been demonstrated, however, that a non-equilibrium magnetisation can appear in the quasiparticle (i.e. excitation) population of a conventional superconductor, with relaxation times on the order of several nanoseconds [6-10]. This raises the question of the spin coherence time of quasiparticles in superconductors and whether this can be measured through resonance experiments analogous to NMR and electron spin resonance (ESR). We have performed such measurements in aluminium and find a quasiparticle spin coherence time of 95+/-20ps.
We have measured the lifetime of spin imbalances in the quasiparticle population of a superconductor ($tau_s$) in the frequency domain. A time-dependent spin imbalance is created by injecting spin-polarised electrons at finite excitation frequencies
into a thin-film mesoscopic superconductor (Al) in an in-plane magnetic field (in the Pauli limit). The time-averaged value of the spin imbalance signal as a function of excitation frequency, $f_{RF}$ shows a cut-off at $f_{RF} approx 1/(2pitau_s)$. The spin imbalance lifetime is relatively constant in the accessible ranges of temperatures, with perhaps a slight increase with increasing magnetic field. Taking into account sample thickness effects, $tau_s$ is consistent with previous measurements and of the order of the electron-electron scattering time $tau_{ee}$. Our data are qualitatively well-described by a theoretical model taking into account all quasiparticle tunnelling processes from a normal metal into a superconductor.
What happens to spin-polarised electrons when they enter a superconductor? Superconductors at equilibrium and at finite temperature contain both paired particles (of opposite spin) in the condensate phase as well as unpaired, spin-randomised quasipar
ticles. Injecting spin-polarised electrons into a superconductor thus creates both spin and charge imbalances [1, 2, 3, 4, 5, 6, 7] (respectively Q* and S*, cf. Ref. [4]). These must relax when the injection stops, but not necessarily over the same time (or length) scale as spin relaxation requires spin-dependent interactions while charge relaxation does not. These different relaxation times can be probed by creating a dynamic equilibrium between continuous injection and relaxation, which leads to constant-in-time spin and charge imbalances. These scale with their respective relaxation times and with the injection current. While charge imbalances in superconductors have been studied in great detail both theoretically [8] and experimentally [9], spin imbalances have not received much experimental attention [6, 10] despite intriguing theoretical predictions of spin-charge separation effects [11, 12]. These could occur e.g. if the spin relaxation time is longer than the charge relaxation time, i.e. Q* relaxes faster than S*. Fundamentally, spin-charge decoupling in superconductors is possible because quasiparticles can have any charge between e and -e, and also because the condensate acts as a particle reservoir [13, 11, 12]. Here we present evidence for an almost-chargeless spin imbalance in a mesoscopic superconductor.
Understanding the flow of spins in magnetic layered structures has enabled an increase in data storage density in hard drives over the past decade of more than two orders of magnitude1. Following this remarkable success, the field of spintronics or s
pin-based electronics is moving beyond effects based on local spin polarisation and is turning its attention to spin-orbit interaction (SOI) effects, which hold promise for the production, detection and manipulation of spin currents, allowing coherent transmission of information within a device. While SOI-induced spin transport effects have been observed in two- and three-dimensional samples, these have been subtle and elusive, often detected only indirectly in electrical transport or else with more sophisticated techniques. Here we present the first observation of a predicted spin-orbit gap in a one-dimensional sample, where counter-propagating spins, constituting a spin current, are accompanied by a clear signal in the easily-measured linear conductance of the system.
In a single-walled carbon nanotube, we observe the spin-1/2 Kondo effect. The energy of spin-resolved Kondo peaks is proportional to magnetic field at high fields, contrary to recent reports. At lower fields, the energy falls below this linear depend
ence, in qualitative agreement with theoretical expectations. For even electron occupancy, we observe a spin-1 Kondo effect due to the degeneracy of the triplet ground states. Tuning gate voltage within the same Coulomb diamond drives a transition to a singlet ground state. We also independently tune the energy difference between singlet and triplet states with a magnetic field. The Zeeman splitting thus measured confirms the value of the g-factor measured from the spin-1/2 Kondo feature.
