Friedels law guarantees an inversion-symmetric diffraction pattern for thin, light materials where a kinematic approximation or a single-scattering model holds. Typically, breaking Friedel symmetry is ascribed to multiple scattering events within thi
ck, non-centrosymmetric crystals. However, two-dimensional (2D) materials such as a single monolayer of MoS$_2$ can also violate Friedels law, with unexpected contrast between conjugate Bragg peaks. We show analytically that retaining higher order terms in the power series expansion of the scattered wavefunction can describe the anomalous contrast between $hkl$ and $overline{hkl}$ peaks that occurs in 2D crystals with broken in-plane inversion symmetry. These higher-order terms describe multiple scattering paths starting from the same atom in an atomically thin material. Furthermore, 2D materials containing heavy elements, such as WS$_2$, always act as strong phase objects, violating Friedels law no matter how high the energy of the incident electron beam. Experimentally, this understanding can enhance diffraction-based techniques to provide rapid imaging of polarity, twin domains, in-plane rotations, or other polar textures in 2D materials.
Materials where the electronic bands have unusual topologies allow for the realization of novel physics and have a wide range of potential applications. When two electronic bands with linear dispersions intersect at a point, the excitations could be
described as Weyl fermions which are massless particles with a particular chirality. Here we report evidence for the presence of Weyl fermions in the ferromagnetic state of the low-carrier density, strongly correlated Kondo lattice system CeSb, from electronic structure calculations and angle-dependent magnetoresistance measurements. When the applied magnetic field is parallel to the electric current, a pronounced negative magnetoresistance is observed within the ferromagnetic state, which is destroyed upon slightly rotating the field away. These results give evidence for CeSb belonging to a new class of Kondo lattice materials with Weyl fermions in the ferromagnetic state.
High purity niobium (Nb), subjected to the processing methods used in the fabrication of superconducting RF cavities, displays micron-sized surface patches containing excess carbon. High-resolution transmission electron microscopy and electron energy
-loss spectroscopy measurements are presented which reveal the presence of nanoscale NbC coherent precipitates in such regions. Raman backscatter spectroscopy on similar surface regions exhibit spectra consistent with the literature results on bulk NbC but with significantly enhanced two-phonon scattering. The unprecedented strength and sharpness of the two-phonon signal has prompted a theoretical analysis, using density functional theory (DFT), of phonon modes in NbC for two different interface models of the coherent precipitate. One model leads to overall compressive strain and a comparison to ab-initio calculations of phonon dispersion curves under uniform compression of the NbC shows that the measured two-phonon peaks are linked directly to phonon anomalies arising from strong electron-phonon interaction. Another model of the extended interface between Nb and NbC, studied by DFT, gives insight into the frequency shifts of the acoustic and optical mode density of states measured by first order Raman. The exact origin of the stronger two-phonon response is not known at present but it suggests the possibility of enhanced electron-phonon coupling in transition metal carbides under strain found either in the bulk NbC inclusions or at their interfaces with Nb metal. Preliminary tunneling studies using a point contact method show some energy gaps larger than expected for bulk NbC.
We present ALMA Cycle-0 observations of the CO (6-5) line emission and of the 435um dust continuum emission in the central kpc of NGC 1614, a local luminous infrared galaxy (LIRG) at a distance of 67.8 Mpc (1 arcsec = 329 pc). The CO emission is well
resolved by the ALMA beam (0.26 x 0.20) into a circum-nuclear ring, with an integrated flux of f_{CO(6-5)} = 898 (+-153) Jy km/s, which is 63(+-12)% of the total CO(6-5) flux measured by Herschel. The molecular ring, located between 100pc < r < 350pc from the nucleus, looks clumpy and includes seven unresolved (or marginally resolved) knots with median velocity dispersion of 40 km/s. These knots are associated with strong star formation regions with Sigma_{SFR} 100 M_sun/yr/kpc^{2} and Sigma_{Gas} 1.0E4 M_sun/pc^{2}. The non-detections of the nucleus in both the CO (6-5) line emission and the 435um continuum rule out, with relatively high confidence, a Compton-thick AGN in NGC 1614. Comparisons with radio continuum emission show a strong deviation from an expected local correlation between Sigma_{Gas} and Sigma_{SFR}, indicating a breakdown of the Kennicutt-Schmidt law on the linear scale of 100 pc.
We present ALMA Cycle-0 observations of the CO (6-5) line emission (rest-frame frequency = 691.473 GHz) and of the 435$mu m$ dust continuum emission in the nuclear region of NGC 34, a local luminous infrared galaxy (LIRG) at a distance of 84 Mpc (1 =
407 pc) which contains a Seyfert 2 active galactic nucleus (AGN) and a nuclear starburst. The CO emission is well resolved by the ALMA beam ($rm 0.26times 0.23$), with an integrated flux of $rm f_{CO~(6-5)} = 1004; (pm 151) ; Jy; km; s^{-1}$. Both the morphology and kinematics of the CO (6-5) emission are rather regular, consistent with a compact rotating disk with a size of 200 pc. A significant emission feature is detected on the red-shifted wing of the line profile at the frequency of the $rm H^{13}CN; (8-7)$ line, with an integrated flux of $rm 17.7 pm 2.1 (random) pm 2.7 (sysmatic); Jy;km; s^{-1}$. However, it cannot be ruled out that the feature is due to an outflow of warm dense gas with a mean velocity of $rm 400; km; s^{-1}$. The continuum is resolved into an elongated configuration, and the observed flux corresponds to a dust mass of $rm M_{dust} = 10^{6.97pm 0.13}; M_{sun}$. An unresolved central core ($rm radius simeq 50; pc$) contributes $28%$ of the continuum flux and $19%$ of the CO (6-5) flux, consistent with insignificant contributions of the AGN to both emissions. Both the CO (6-5) and continuum spatial distributions suggest a very high gas column density ($rm >= 10^4; M_{sun}; pc^{-2}$) in the nuclear region at $rm radius <= 100; pc$.
We show that noncollinear Andreev reflections can be induced at interfaces of semiconductor nanowires with spin-orbit coupling, Zeeman splitting and proximity-induced superconductivity. In a noncollinear local Andreev reflection, the spin polarizatio
ns of the injected and the retro-reflected carriers are typically at an angle which is tunable via system parameters. While in a nonlocal transport, this noncollinearity enables us to identify and block, at different voltage configurations, the noncollinear cross Andreev reflection and the direct charge transfer processes. We demonstrate that the intriguing noncollinearity originates from the spin-dependent coupling between carriers in the lead and the lowest discrete states in the wire, which, for a topological superconducting nanowire, are related to the overlap-induced hybridization of Majorana edge states in a finite system. These interesting phenomena can be observed in semiconductor nanowires of experimentally relevant lengths, and are potentially useful for spintronics.
The magnetic phase diagram has been mapped out via the measurements of electronic resistivity, magnetization and specific heat in the cobalt-based layered LnCo1-xFexAsO (Ln=La, Sm) compounds. The ferromagnetic (FM) transition at 63 K for LaCoAsO is r
apidly suppressed upon Fe doping, and ultimately disappears around x=0.3 in the LaCo1-xFexAsO system. When La is replaced by magnetic rare earth element Sm, the 3d electrons first undergo a FM transition at Tc = 75 K, followed by an antiferromagnetic (AFM) transition at a lower temperature TN1 = 45 K. With partial Fe doping on the Co site, both FM (Tc) and AFM (TN1) transition temperatures are significantly suppressed, and finally approach zero kelvin at x = 0.3 and 0.2, respectively. Meanwhile, a third magnetic transition at TN2 = 5.6 K for SmCoAsO, associated with the AFM order of the Sm3+ 4f-oments, is uncovered and TN2 is found to be almost robust against the small Fe-doping. These results suggest that the 4f electrons of Sm3+ have an important effect on the magnetic behavior of 3d electrons in the 1111 type Co-based LnCo1-xFexAsO systems. In contrast, the magnetism of the f-electrons is relatively unaffected by the variation of the 3d electrons. The rich magnetic phase diagram in the Co-rich side of the LnCo1-xFexAsO system, therefore, is established.
We investigate the dual roles of a cobalt impurity in the Ba-122 ferropnictide superconductor in the state with coexisting collinear spin density wave (SDW) order as a dopant and as a scattering center, using first principles electronic structure met
hods. The Co atom is found to dope the FeAs plane where it is located with a single delocalized electron as expected, but also induces a strong perturbation of the SDW ground state of the system. This in turn induces a stripe-like modulation of the density of states in nearby planes which may be observable in STM experiments. The defect is found to have an intermediate strength nonmagnetic scattering potential with a range of roughly 1 Angstrom, and the Co gives rise to a smaller but longer range magnetic scattering potential. The impurity potential in both channels is highly anisotropic, reflecting the broken symmetry of the SDW ground state. We give values for the effective Co potentials for each d orbital on the impurity and nearby sites. The calculation also shows a clear local resonance comprised of Co states about 200meV above the Fermi level, in quantitative agreement with a recent report from STM. Finally, we discuss the issue of the effective dimensionality of the 122 materials, and show that the hybridization of the out-of-phase As atoms leads to a higher density of states between the FeAs planes relative to the 1111 counterparts.
