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Previous estimates of the solar flare abundances of Si, S, Cl, Ar, and K from the RESIK X-ray crystal spectrometer on board the CORONAS-F spacecraft were made on the assumption of isothermal X-ray emission. We investigate the effect on these estimate s by relaxing this assumption and instead determining the differential emission measure (DEM) or thermal structure of the emitting plasma by re-analyzing RESIK data for a GOES class M1.0 flare on 2002 November~14 (SOL2002-11-14T22:26) for which there was good data coverage. The analysis method uses a maximum-likelihood (Withbroe--Sylwester) routine for evaluating the DEM. In a first step, called here AbuOpt, an optimized set of abundances of Si, S, Ar, and K is found that is consistent with the observed spectra. With these abundances, the differential emission measure evolution during the flare is found. The abundance optimization leads to revised abundances of silicon and sulfur in the flare plasma: $A({rm S}) = 6.94 pm 0.06$ and $A({rm Si}) = 7.56 pm 0.08$ (on a logarithmic scale with $A({rm H}) = 12$). Previously determined abundances of Ar, K, and Cl from an isothermal assumption are still the preferred values. During the flares maximum phase, the X-ray-emitting plasma has a basically two-temperature structure, with the cooler plasma with approximately constant temperature (3--6~MK) and a hotter plasma with temperature $16-21$~MK. Using imaging data from the RHESSI hard X-ray spacecraft, the emission volume of the hot plasma is deduced from which lower limits of the electron density $N_e$ and the thermal content of the plasma are given.
The RESIK instrument on the CORONAS-F spacecraft obtained solar flare and active region X-ray spectra in four channels covering the wavelength range 3.8 -- 6.1 AA in its operational period between 2001 and 2003. Several highly ionized silicon lines w ere observed within the range of the long-wavelength channel (5.00 -- 6.05 AA). The fluxes of the sixiv Ly-$beta$ line (5.217 AA) and the sixiii $1s^2 - 1s3p$ line (5.688 AA) during 21 flares with optimized pulse-height analyzer settings on RESIK have been analyzed to obtain the silicon abundance relative to hydrogen in flare plasmas. As in previous work, the emitting plasma for each spectrum is assumed to be characterized by a single temperature and emission measure given by the ratio of emission in the two channels of GOES. The silicon abundance is determined to be $A({rm Si}) = 7.93 pm .21$ (sixiv) and $7.89 pm .13$ (sixiii) on a logarithmic scale with H = 12. These values, which vary by only very small amounts from flare to flare and times within flares, are $2.6 pm 1.3$ and $2.4 pm 0.7$ times the photospheric abundance, and are about a factor of three higher than RESIK measurements during a period of very low activity. There is a suggestion that the Si/S abundance ratio increases from active regions to flares.
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