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76 - B. S. Wang , P. Tong , Y. P. Sun 2009
The temperature dependences of magnetization, electrical transport, and thermal transport properties of antiperovskite compound SnCMn3 have been investigated systematically. A positive magnetoresistance (~11%) is observed around the ferrimagnetic-par amagnetic transition (TC ~ 280 K) in the field of 50 kOe, which can be attributed to the field-induced magnetic phase transition. The abnormalities of resistivity, Seebeck coefficient, normal Hall effect and thermal conductivity near TC are suggested to be associated with an abrupt reconstruction of electronic structure. Further, our results indicate an essential interaction among lattice, spin and charge degrees of freedom around TC. Such an interaction among various degrees of freedom associated with sudden phase transition is suggested to be characteristic of Mn-based antiperovskite compounds.
62 - B. S. Wang , P. Tong , Y. P. Sun 2009
We report the observation of large magnetocaloric effect near room temperature in antipervoskite SnCMn3. The maximal magnetic entropy change at the first-order ferrimagnetic-paramagnetic transition temperature (TC 279 K) is about 80.69mJ/cm3 K and 13 3mJ/cm3 K under the magnetic field of 20 kOe and 48 kOe, respectively. These values are close to those of typical magnetocaloric materials. The large magnetocaloric effect is associated with the sharp change of lattice, resistivity and magnetization in the vicinity of TC. Through the measurements of Seebeck coefficient and normal Hall effect, the title system is found to undergo a reconstruction of electronic structure at TC. Considering its low-cost and innocuous raw materials, Mn-based antiperovskite compounds are suggested to be appropriate for pursuing new materials with larger magnetocaloric effect.
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