We attempt to confirm bright non-LTE emission from the exoplanet HD189733b at 3.25 microns, as recently reported by Swain et al. (2010) based on observations at low spectral resolving power (R ~ 30). Non-LTE emission lines from gas in an exoplanet at
mosphere will not be significantly broadened by collisions, so the measured emission intensity per resolution element must be substantially brighter when observed at high spectral resolving power. We observed the planet before, during, and after a secondary eclipse event at a resolving power R = 27,000 using the NIRSPEC spectrometer on the Keck II telescope. Our spectra cover a spectral window near the peak found by Swain et al., and we compare emission cases that could account for the magnitude and wavelength dependence of the Swain et al. result with our final spectral residuals. To model the expected line emission, we use a general non-equilibrium formulation to synthesize emission features from all plausible molecules that emit in this spectral region. In every case, we detect no line emission to a high degree of confidence. After considering possible explanations for the Swain et al. results and the disparity with our own data, we conclude that an astrophysical source for the putative non-LTE emission is unlikely. We note that the wavelength dependence of the signal seen by Swain et al. closely matches the 2nu2 band of water vapor at 300K, and we suggest that an imperfect correction for telluric water is the source of the feature claimed by Swain et al.
We detect emission from multiple low-excitation ro-vibrational transitions of OH from the two Herbig Ae stars AB Aurigae and MWC 758 in the 3.0 - 3.7 micron wavelength range (L-band), using the NIRSPEC instrument on Keck II. The inner radius for the
emitting region in both stars is close to 1 AU. We compare an optically thin LTE model and a thin-wedge fluorescence model, finding rotational temperatures of 650 - 800 K and OH abundances of 10^42 - 10^45 molecules for the two stars. Comparisons with current chemical models support the fluorescence excitation model for AB Aurigae and possibly MWC 758, but further observations and detailed modeling are necessary to improve constraints on OH emission in different disk environments.
