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The G333 giant molecular cloud contains a few star clusters and H II regions, plus a number of condensations currently forming stars. We have mapped 13 of these sources with the appearance of young stellar objects (YSOs) with the Spitzer Infrared Spe ctrograph in the SL, SH, and LH modules (5-36 micron). We use these spectra plus available photometry and images to characterize the YSOs. The spectral energy distributions (SEDs) of all sources peak between 35 and 110 micron, thereby showing their young age. The objects are divided into two groups: YSOs associated with extended emission in IRAC band 2 at 4.5 micron (`outflow sources) and YSOs that have extended emission in all IRAC bands peaking at the longest wavelengths (`red sources). The two groups of objects have distinctly different spectra: All the YSOs associated with outflows show evidence of massive envelopes surrounding the protostar because the spectra show deep silicate absorption features and absorption by ices at 6.0, 6.8, and 15.2 micron. We identify these YSOs with massive envelopes cool enough to contain ice-coated grains as the `bloated protostars in the models of Hosokawa et al. All spectral maps show ionized forbidden lines and PAH emission features. For four of the red sources, these lines are concentrated to the centres of the maps, from which we infer that these YSOs are the source of ionizing photons. Both types of objects show evidence of shocks, with most of the outflow sources showing a line of [S I] in the outflows and two of the red sources showing the more highly excited [Ne III] and [S IV] lines in outflow regions at some distance from the YSOs. The 4.5 micron emission seen in the IRAC band 2 images of the outflow sources is not due to H2 lines, which are too faint in the 5-10 micron wavelength region to be as strong as is needed to account for the IRAC band 2 emission.
We report on the discovery of a luminous blue variable (LBV) lying ~7 pc in projection from the Quintuplet cluster. This source, which we call LBV G0.120-0.048, was selected for spectroscopy owing to its detection as a strong source of Paschen-alpha excess in a recent narrowband imaging survey of the Galactic center region with HST/NICMOS. The K-band spectrum is similar to that of the Pistol Star and other known LBVs. The new LBV was previously cataloged as a photometric variable star, exhibiting brightness fluctuations of up to ~1 mag between 1994 and 1997, with significant variability also occurring on month-to-month time scales. The luminosity of LBV G0.120-0.048, as derived from 2MASS photometry, is approximately equivalent to that of the Pistol Star. However, the time-averaged brightness of LBV G0.120-0.048 between 1994 and 1997 exceeded that of the Pistol Star; LBV G0.120-0.048 also suffers more extinction, which suggests that it was intrinsically more luminous in the infrared than the Pistol Star between 1994 and 1997. Paschen-alpha images reveal a thin circular nebula centered on LBV G0.120-0.048 with a physical radius of ~0.8 pc. We suggest that this nebula is a shell of ejected material launched from a discrete eruption that occurred between 5000 and 10,000 years ago. Because of the very short amount of time that evolved massive stars spend in the LBV phase, and the close proximity of LBV G0.120-0.048 to the Quintuplet cluster, we suggest that this object might be coeval with the cluster and may have once resided within it.
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