We investigate how short and long electron trajectory contributions to high harmonic emission and their interferences give access to intra-molecular dynamics. In the case of unaligned molecules, we show experimental evidences that the long trajectory
signature is more dependent upon the molecule than the short one, providing a high sensitivity to cation nuclear dynamics within 100s of as to few fs. Using theoretical approaches based on Strong Field Approximation and Time Dependent Schrodinger Equation, we examine how quantum path interferences encode electronic motion whilst molecules are aligned. We show that the interferences are dependent on channels superposition and upon which ionisation channel is involved. In particular, quantum path interferences encodes electronic migration signature while coupling between channels is allowed by the laser field. Hence, molecular quantum path interferences is a promising method for Attosecond Spectroscopy, allowing the resolution of ultra-fast charge migration in molecules after ionisation in a self-referenced manner.
