We present Hubble Space Telescope optical and near-IR transmission spectra of the transiting hot-Jupiter WASP-31b. The spectrum covers 0.3-1.7 $mu$m at a resolution $Rsim$70, which we combine with Spitzer photometry to cover the full-optical to IR. T
he spectrum is dominated by a cloud-deck with a flat transmission spectrum which is apparent at wavelengths $>0.52mu$m. The cloud deck is present at high altitudes and low pressures, as it covers the majority of the expected optical Na line and near-IR H$_2$O features. While Na I absorption is not clearly identified, the resulting spectrum does show a very strong potassium feature detected at the 4.2-$sigma$ confidence level. Broadened alkali wings are not detected, indicating pressures below $sim$10 mbar. The lack of Na and strong K is the first indication of a sub-solar Na/K abundance ratio in a planetary atmosphere (ln[Na/K]$=-3.3pm2.8$), which could potentially be explained by Na condensation on the planets night side, or primordial abundance variations. A strong Rayleigh scattering signature is detected at short wavelengths, with a 4-$sigma$ significant slope. Two distinct aerosol size populations can explain the spectra, with a smaller sub-micron size grain population reaching high altitudes producing a blue Rayleigh scattering signature on top of a larger, lower-lying population responsible for the flat cloud deck at longer wavelengths. We estimate that the atmospheric circulation is sufficiently strong to mix micron size particles upward to the required 1-10 mbar pressures, necessary to explain the cloud deck. These results further confirm the importance of clouds in hot-Jupiters, which can potentially dominate the overall spectra and may alter the abundances of key gaseous species.
We compute models of the transmission spectra of planets HD 209458b, HD 189733b, and generic hot Jupiters. We examine the effects of temperature, surface gravity, and metallicity for the generic planets as a guide to understanding transmission spectr
a in general. We find that carbon dioxide absorption at 4.4 and 15 microns is prominent at high metallicity, and is a clear metallicity indicator. For HD 209458b and HD 189733b, we compute spectra for both one-dimensional and three-dimensional model atmospheres and examine the differences between them. The differences are usually small, but can be large if atmospheric temperatures are near important chemical abundance boundaries. The calculations for the 3D atmospheres, and their comparison with data, serve as constraints on these dynamical models that complement the secondary eclipse and light curve data sets. For HD 209458b, even if TiO and VO gases are abundant on the day side, their abundances can be considerably reduced on the cooler planetary limb. However, given the predicted limb temperatures and TiO abundances, the models optical opacity is too high. For HD 189733b we find a good match with some infrared data sets and constrain the altitude of a postulated haze layer. For this planet, substantial differences can exist between the transmission spectra of the leading and trailing hemispheres, which is an excellent probe of carbon chemistry. In thermochemical equilibrium, the cooler leading hemisphere is methane-dominated, and the hotter trailing hemisphere is CO-dominated, but these differences may be eliminated by non-equilibrium chemistry due to vertical mixing. It may be possible to constrain the carbon chemistry of this planet, and its spatial variation, with JWST.
