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From the rate of hydrogen ionization and the gamma ray flux, we derived the spectrum of relativistic and subrelativistic cosmic rays (CRs) nearby and inside the molecular cloud Sgr B2 near the Galactic Center (GC). We studied two cases of CR propagat ion in molecular clouds: free propagation and scattering of particles by magnetic fluctuations excited by the neutral gas turbulence. We showed that in the latter case CR propagation inside the cloud can be described as diffusion with the coefficient $sim 3times 10^{27}$ cm$^2$ s$^{-1}$. For the case of hydrogen ionization by subrelativistic protons, we showed that their spectrum outside the cloud is quite hard with the spectral index $delta>-1$. The energy density of subrelativistic protons ($>50$ eV cm$^{-3}$) is one order of magnitude higher than that of relativistic CRs. These protons generate the 6.4 keV emission from Sgr B2, which was about 30% of the flux observed by Suzaku in 2013. Future observations for the period after 2013 may discover the background flux generated by subrelativistic CRs in Sgr B2. Alternatively hydrogen ionization of the molecular gas in Sgr B2 may be caused by high energy electrons. We showed that the spectrum of electron bremsstrahlung is harder than the observed continuum from Sgr B2, and in principle this X-ray component provided by electrons could be seen from the INTEGRAL data as a stationary high energy excess above the observed spectrum $E_x^{-2}$.
We analyse the 6.4 keV iron line component produced in the Galactic Center (GC) region by cosmic rays in dense molecular clouds (MCs) and in the diffuse molecular gas. We showed that this component, in principle, can be seen in several years in the d irection of the cloud Srg B2. If this emission is produced by low energy CRs which ionize the interstellar molecular gas the intensity of the line is quite small, < 1%. However, we cannot exclude that local sources of CRs or X-ray photons nearby the cloud may provide much higher intensity of the line from there. Production of the line emission from molecular clouds depends strongly on processes of CR penetration into them. We show that turbulent motions of neutral gas may generate strong magnetic fluctuations in the clouds which prevent free penetration of CRs into the clouds from outside. We provide a special analysis of the line production by high energy electrons. We concluded that these electrons hardly provide the diffuse 6.4 keV line emission from the GC because their density is depleted by ionization losses. We do not exclude that local sources of electrons may provide an excesses of the 6.4 keV line emission in some molecular clouds and even reproduce a relatively short time variations of the iron line emission. However, we doubt whether a single electron source provides the simultaneous short time variability of the iron line emission from clouds which are distant from each other on hundred pc as observed for the GC clouds. An alternative speculation is that local electron sources could also provide the necessary effect of the line variations in different clouds that are seen simultaneously by chance that seems, however, very unlikely.
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