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Register a new userEffect of O3 on the atmospheric temperature structure of early Mars
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Ozone is an important radiative trace gas in the Earths atmosphere. The presence of ozone can significantly influence the thermal structure of an atmosphere, and by this e.g. cloud formation. Photochemical studies suggest that ozone can form in carbon dioxide-rich atmospheres. We investigate the effect of ozone on the temperature structure of simulated early Martian atmospheres. With a 1D radiative-convective model, we calculate temperature-pressure profiles for a 1 bar carbon dioxide atmosphere. Ozone profiles are fixed, parameterized profiles. We vary the location of the ozone layer maximum and the concentration at this maximum. The maximum is placed at different pressure levels in the upper and middle atmosphere (1-10 mbar). Results suggest that the impact of ozone on surface temperatures is relatively small. However, the planetary albedo significantly decreases at large ozone concentrations. Throughout the middle and upper atmospheres, temperatures increase upon introducing ozone due to strong UV absorption. This heating of the middle atmosphere strongly reduces the zone of carbon dioxide condensation, hence the potential formation of carbon dioxide clouds. For high ozone concentrations, the formation of carbon dioxide clouds is inhibited in the entire atmosphere. In addition, due to the heating of the middle atmosphere, the cold trap is located at increasingly higher pressures when increasing ozone. This leads to wetter stratospheres hence might increase water loss rates on early Mars. However, increased stratospheric H2O would lead to more HOx, which could efficiently destroy ozone. This result emphasizes the need for consistent climate-chemistry calculations to assess the feedback between temperature structure, water content and ozone chemistry. Furthermore, convection is inhibited at high ozone amounts, leading to a stably stratified atmosphere.
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Context. Observationally constraining the atmospheric temperature-pressure (TP) profile of exoplanets is an important step forward for improving planetary atmosphere models, further enabling one to place the detection of spectral features and the measurement of atomic and molecular abundances through transmission and emission spectroscopy on solid ground. Aims. The aim is to constrain the TP profile of the ultra-hot Jupiter KELT-9b by fitting synthetic spectra to the observed H$alpha$ and H$beta$ lines and identify why self-consistent planetary TP models are unable to fit the observations. Methods. We construct 126 one-dimensional TP profiles varying the lower and upper atmospheric temperatures, as well as the location and gradient of the temperature rise. For each TP profile, we compute transmission spectra of the H$alpha$ and H$beta$ lines employing the Cloudy radiative transfer code, which self-consistently accounts for non-local thermodynamic equilibrium (NLTE) effects. Results. The TP profiles leading to best fit the observations are characterised by an upper atmospheric temperature of 10000-11000 K and by an inverted temperature profile at pressures higher than 10$^{-4}$ bar. We find that the assumption of local thermodynamic equilibrium (LTE) leads to overestimate the level population of excited hydrogen by several orders of magnitude, and hence to significantly overestimate the strength of the Balmer lines. The chemical composition of the best fitting models indicate that the high upper atmospheric temperature is most likely driven by metal photoionisation and that FeII and FeIII have comparable abundances at pressures lower than 10$^{-6}$ bar, possibly making the latter detectable. Conclusions. Modelling the atmospheres of ultra-hot Jupiters requires one to account for metal photoionisation. [abridged]
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