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Register a new userQuadratic transverse anisotropy term due to dislocations in Mn12-Ac directly obtained by EPR spectroscopy
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High-Sensitivity Electron Paramagnetic Resonance experiments have been carried out in fresh and stressed Mn12-Acetate single crystals for frequencies ranging from 40 GHz up to 110 GHz. The high number of crystal dislocations formed in the stressing process introduces a E(S_x^2-S_y^2) transverse anisotropy term in the spin hamiltonian. From the behaviour of the resonant absorptions on the applied transverse magnetic field we have obtained an average value for E = 22 mK, corresponding to a concentration of dislocations per unit cell of c = 10^-3.
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The problem of the role of transverse fields in Mn12-acetate, a molecular nanomagnet, is still open. We present structural evidences that the disorder of the acetic acid of crystallization indices sizeable distortion of the Mn(III) sites, giving rise to six different isomers, four of them with symmetry lower than tetragonal. Using a ligand field approach the effect of the structure modifications on the second order transverse magnetic anisotropy, forbidden in tetragonal symmetry, has been evaluated. The order of magnitude of the quadratic transverse anisotropies well agree with the values derived by the analysis of the field sweep dependence of the hysteresis loops performed by Mertes et al. (Phys. Rev. Lett 87, 227205 (2001)) and allows to better simulate the EPR spectra.
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We theoretically investigate the effect of transverse magnetic anisotropy on spin-flip assisted tunneling through atomic spin chains. Using a phenomenological approach and first-order perturbation theory, we analytically calculate the inelastic tunneling current, differential conductance and atomic spin transition rates. We predict the appearance of additional steps in the differential conductance and a pronounced increase in the spin-flip transition rate which at low voltages scale quadratically with the ratio of the transverse anisotropy energy and the sum of the longitudinal anisotropy energy and the exchange energy. Our results provide intuitive quantitative insight in the role played by transverse anisotropy in inelastic tunneling spectroscopy of atomic chains and can be observed under realistic experimental conditions.
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