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Register a new userSingle crystal MgB2 with anisotropic superconducting properties
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The discovery of superconductor in magnesium diboride MgB2 with high Tc (39 K) has raised some challenging issues; whether this new superconductor resembles a high temperature cuprate superconductor(HTS) or a low temperature metallic superconductor; which superconducting mechanism, a phonon- mediated BCS or a hole superconducting mechanism or other new exotic mechanism may account for this superconductivity; and how about its future for applications. In order to clarify the above questions, experiments using the single crystal sample are urgently required. Here we have first succeeded in obtaining the single crystal of this new MgB2 superconductivity, and performed its electrical resistance and magnetization measurements. Their experiments show that the electronic and magnetic properties depend on the crystallographic direction. Our results indicate that the single crystal MgB2 superconductor shows anisotropic superconducting properties and thus can provide scientific basis for the research of its superconducting mechanism and its applications.
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In-plane electrical transport properties of MgB2 single crystals grown under high pressure of 4-6 GPa and temperature of 1400-1700oC in Mg-B-N system have been measured. For all specimens we found sharp superconducting transition around 38.1-38.3K with transition width within 0.2-0.3K. Estimated resistivity value at 40K is about 1 mkOhmcm and resistivity ratio R(273K)/R(40K) of about 4.9. Results of measurements in magnetic field up to 5.5T perpendicular to Mg and B planes and up to 9T in parallel orientation show temperature dependent anisotropy of the upper critical field with anisotropy ratio increasing from 2.2 close to Tc up to about 3 below 30K. Strong deviation of the angular dependence of Hc2 from anisotropic mass model has been also found.
Here we report the growth of sub-millimeter MgB2 single crystals of various shapes under high pressure in Mg-B-N system. Structure refinement using a single-crystal X-ray diffraction analysis gives lattice parameters a=3.0851(5) A and c=3.5201(5) A with small reliability factors (Rw =0.025, R=0.018), which enables us to analyze the Fourier and Fourier difference maps. The maps clearly show the B sp2 orbitals and covalency of the B-B bonds. The sharp superconducting transitions at Tc =38.1-38.3K were obtained in both magnetization (DTc =0.6K) and resistivity (DTc <0.3K) measurements. Resistivity measurements with magnetic fields applied parallel and perpendicular to the Mg and B sheets reveal the anisotropic nature of this compound, with upper critical field anisotropy ratio of about 2.7.
The superconducting phase diagram of MgB2 was determined from magnetization, magneto-transport and the first single-crystal specific heat measurements. A zero-temperature in-plane coherence length of 8 nm is determined. The superconducting anisotropy increases from a value around 2 near Tc to above 4.5 at 22 K. For H||c a pronounced peak effect in the critical current occurs at the upper critical field. Evidence for a surface superconducting state is presented for H||c which might account for the wide spread in reported values of the anisotropy.
We discuss the important aspects of synthesis and crystal growth of MgB2 under high pressure (P) and temperature (T) in Mg-B-N system, including the optimisation of P-T conditions for reproducible crystal growth, the role of liquid phases in this process, the temperature dependence of crystal size and the effect of growing instabilities on single crystals morphology. Extensive experiments have been carried out on single crystals with slightly different lattice constants and defects concentration, which revealed and possible effects of Mg-deficiency and lattice strain on the superconducting properties of MgB2 (Tc, Jc, residual resistivity ratio, anisotropy etc.).
Anisotropic properties of superconducting MgB2 obtained by torque magnetometry are compared to theoretical predictions, concentrating on two issues. Firstly, the angular dependence of Hc2 is shown to deviate close to Tc from the dependence assumed by anisotropic Ginzburg-Landau theory. Secondly, from the evaluation of torque vs angle curves it is concluded that the anisotropy of the penetration depth gamma_lambda has to be substantially higher at low temperature than theoretical estimates, at least in fields higher than 0.2 T.
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