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Modeling chemistry during star formation: Water deuteration in dynamic star-forming regions

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 Publication date 2021
  fields Physics
and research's language is English




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Recent observations of the HDO/H$_2$O ratio toward protostars in isolated and clustered environments show an apparent dichotomy, where isolated sources show higher D/H ratios than clustered counterparts. Establishing which physical and chemical processes create this differentiation can provide insights into the chemical evolution of water during star formation and the chemical diversity during the star formation process and in young planetary systems. Methods: The evolution of water is modeled using 3D physicochemical models of a dynamic star-forming environment. The physical evolution during the protostellar collapse is described by tracer particles from a 3D MHD simulation of a molecular cloud region. Each particle trajectory is post-processed using RADMC-3D to calculate the temperature and radiation field. The chemical evolution is simulated using a three-phase grain-surface chemistry model and the results are compared with interferometric observations of H$_2$O, HDO, and D$_2$O in hot corinos toward low-mass protostars. Results: The physicochemical model reproduces the observed HDO/H$_2$O and D$_2$O/HDO ratios in hot corinos, but shows no correlation with cloud environment for similar identical conditions. The observed dichotomy in water D/H ratios requires variation in the initial conditions (e.g., the duration and temperature of the prestellar phase). Reproducing the observed D/H ratios in hot corinos requires a prestellar phase duration $tsim$1-3 Myr and temperatures in the range $T sim$ 10-20 K prior to collapse. This work demonstrates that the observed differentiation between clustered and isolated protostars stems from differences in the molecular cloud or prestellar core conditions and does not arise during the protostellar collapse itself.



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(abridged) Data and results from the WISH key program are summarized, designed to provide a legacy data set to address its physics and chemistry. WISH targeted ~80 sources along the two axes of luminosity and evolutionary stage: from low- to high-mass protostars and from pre-stellar cores to protoplanetary disks. Lines of H2O, HDO, OH, CO and [O I] were observed with the HIFI and PACS instruments, complemented by molecules that probe UV, X-ray or grain chemistry. Most of the far-infrared water emission from protostars is found to be compact, originating from warm outflowing and shocked gas at high density and temperature in at least two physical components. This gas is not probed by low-J CO lines, only by J>14. Water is a significant, but not dominant, coolant. Its abundance is universally low, of order H2O/H2=2E-6, pointing to shock and outflow cavity models that include UV radiation at 100-1000 times the ISRF. In cold quiescent pre-stellar cores and envelopes, the water abundance structure is accurately probed through velocity-resolved line profiles, confirming basic chemistry networks. The gaseous HDO/H2O ratio of 0.025, much higher than that of bulk ice, is representative of the outer photodesorbed ice layers and cold chemistry. Water abundances in the inner hot cores are high, but with variations from 5E-6 to 2E-4. Combined analyses of water gas and ice show that up to 50% of the oxygen budget may be missing, with possible explanations discussed. Water vapor emission from disks is weak, indicating that water ice is locked up in larger pebbles early on and that these pebbles have settled and drifted inward by the Class II stage. Quantitatively, many oceans of water ice are available. Extragalactic low-J H2O emission is mostly compact and collisionally excited. Prospects for future mid- to far-infrared missions are given.
VLBI multi-epoch water maser observations are a powerful tool to study the dense, warm shocked gas very close to massive protostars. The very high-angular resolution of these observations allow us to measure the proper motions of the masers in a few weeks, and together with the radial velocity, to determine their full kinematics. In this paper we present a summary of the main observational results obtained toward the massive star-forming regions of Cepheus A and W75N, among them: (i) the identification of different centers of high-mass star formation activity at scales of 100 AU; (ii) the discovery of new phenomena associated with the early stages of high-mass protostellar evolution (e.g., isotropic gas ejections); and (iii) the identification of the simultaneous presence of a wide-angle outflow and a highly collimated jet in the massive object Cep A HW2, similar to what is observed in some low-mass protostars. Some of the implications of these results in the study of high-mass star formation are discussed.
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